Korean Journal of Chemical Engineering, Vol.27, No.3, 785-790, March, 2010
Kinetic model of glycerol chlorination with hydrochloric acid
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A new reaction model for dichloropropanol (DCP) synthesis from glycerol chlorination is proposed based on the models reported by Tesser et al. (2007) and Luo et al. (2009). Two reaction steps, glycerol to glycerol-1-acetate and α-MCP to 3-chloropropandiol-1-acetate, were defined as reversible reactions and other reaction steps were defined as irreversible processes. Using the experimental data reported by Luo et al. (2009), the values predicted in this study were compared with the previous model reported by Luo et al. (2009) using both the average absolute deviation (AAD) and root mean square deviation (RMSD). The AAD and RMSD of the new model were 31% and 33% lower than that of the existing one, respectively. Overall, the proposed model for glycerol chlorination is superior to the previous model.
- Bell BM, Briggs JR, Campbell RM, Chambers SM, Gaarenstroom PD, Hippler JG, Hook BD, Kearns K, Kenney JM, Kruper WJ, Schreck DJ, Theriault CN, Wolfe CP, Clean, 36, 657 (2008)
- Behr A, Eilting J, Irawadi LK, Lindner F, Green Chemistry, 10, 13 (2008)
- German Patent Nr. 197308 (1906)
- German Patent Nr. 197309 (1906)
- German Patent Nr. 238341 (1908)
- Conant JB, Qualye OR, Organic Synthesis, Coll., 1, 294 (1941)
- Conant JB, Qualye OR, Organic Synthesis, Coll., 1, 292 (1941)
- Pavel K, Petr S, Ivanapct B, PCT Patent WO2005/021476 (2005)
- Philippe K, Patrick G, Benoit G, Sara C, PCT Patent WO2005/054167 (2005)
- Schreck DJ, Kruper WJ, Varjian RD, Jones ME, Campbell RM, Kearns K, Hook BD, Briggs JR, Hippler JG, PCT Patent WO2006/020234 (2006)
- Philippe K, Franck C, De Ivan A, Veyrac R, PCT Patent WO2007/054505 (2005)
- Siano D, Santacesaria E, Fiandra V, Tesser R, Di Nuzzi G, Di Serio M, Nastasi M, PCT Patent WO2006/111810 (2006)
- Lee SH, Park DR, Kim HS, Lee JH, Jung JC, Woo SY, Song WS, Kwon MS, Song IK, Catalysis Communications, 9, 1920 (2008)
- Lee SH, Park DR, Kim H, Lee J, Jung JC, Woo SY, Song WS, Kwon MS, Song IK, Korean J. Chem. Eng., 25(5), 1018 (2008)
- Lee SH, Park DR, Kim HS, Lee JH, Jung JC, Park SY, Cho KM, Song IK, React. Kinet. Catal. Lett., 94, 1 (2008)
- Lee SH, Song SH, Park DR, Jung JC, Song JH, Woo SY, Song WS, Kwon MS, Song IK, Catalysis Communications, 10, 160 (2008)
- Song SH, Lee SH, Park DR, Kim HS, Woo SY, Song WS, Kwon MS, Song IK, Korean J. Chem. Eng., 26(2), 382 (2009)
- Tesser R, Santacesaria E, Di Serio M, Di Nuzzi G, Fiandra V, Ind. Eng. Chem. Res., 46(20), 6456 (2007)
- Luo ZH, You XZ, Li HR, Ind. Eng. Chem. Res., 48(1), 446 (2009)
- Luo ZH, You XZ, Li HR, Korean J. Chem. Eng., 27(1), 66 (2010)
- Brown WH, Foote CS, Iverson, Organic Chemistry, 4th edition, Brooks/Cole (2005)