화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.27, No.3, 791-801, March, 2010
DOI10.1007/s11814-010-0118-6  Export Citation
Thermogravimetric analysis of longan seed biomass with a two-parallel reactions model
Supunnee Junpirom, Chaiyot Tangsathitkulchai†, and Malee Tangsathitkulchai1
  • School of Chemical Engineering, Institute of Engineering, Suranaree University of Technology, Nakhon Ratchasima 30000, Thailand
  • 1School of Chemistry, Institute of Science, Suranaree University of Technology, Nakhon Ratchasima 30000, Thailand
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The kinetic analysis of pyrolysis process of longan seed was performed in a thermogravimetric analyzer. All experimental runs were carried out by using an initial sample mass of 15 mg and final temperature of 650 ℃ under the inert atmosphere of nitrogen. Particle sizes in the range from 0.05-2.1 mm and the heating rates from 5-100 ℃/min were employed to investigate their effects on the thermogram and the kinetic parameters. The TG curves generally showed sigmoid shape and displayed one major peak in DTG curve. The main devolatilization of longan seed occurred over the temperature range of 210-330 ℃. It was found that heat transfer resistance in a particle could be reduced either by decreasing the size of particle or increasing the heating rate. The thermal decomposition of longan seed could be well described by the two-parallel reactions kinetic model. This analysis of reaction kinetic gave the values of activation energy for the decomposition of the two fractions in the model corresponding closely to those of hemicellulose and lignin.
Keywords:Pyrolysis;Devolatilization;Two Parallel Reactions Model;Longan Seed
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