화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.18, No.3, 289-296, March, 2010
DOI10.1007/s13233-010-0313-7  Export Citation
Self-organization of amphiphilic diblock rod-coil molecule into supramolecular honeycomb and cylindrical aggregates and its application as Suzuki coupling reaction
Ke-li Zhong1, Chunchang Yang1, Tie Chen1, Bingzhu Yin1, Long Yi Jin1, 2, †, Zhegang Huang3, and Eunji Lee3
  • 1Department of Chemistry, College of Science and the Key Laboratory for Organism Resources of the Changbai Mountain and Functional Molecules, Yanbian University, Yanji, 133002, P. R. China
  • 2School of Natural Sciences, University of California, Merced, USA
  • 3Department of Chemistry, Yonsei University, Seoul, 120-749, Korea
E-mail:
An aromatic amphiphilic molecule consisting of three biphenyl groups and one styrene unit linked together with ether bonds as a rigid rod segment, and poly(ethylene oxide) with 17 repeating units as a coil segment was synthesized and its self-assembly behavior in the bulk state and aqueous solution was examined by DSC, X-ray scattering, DLS and TEM. This molecule based on a rod building block self-assembles into lamellar or hexagonal perforated layer (HPL) structures in the crystalline phase or liquid crystalline mesophase. In an aqueous medium, the molecule self-assembles into cylindrical aggregates and can be used as a supramolecular reactor for the Suzuki coupling reaction.
Keywords:rod-coil;self-assembly;SAXS;supramolecular-nanoreactor
  1. Lee M, Cho BK, Zin WC, Chem. Rev., 101(12), 3869 (2001)
  2. Vriezema DM, Aragones MC, Elemans JAAW, Cornelissen JJLM, Rowan AE, Nolte RJM, Chem. Rev., 105(4), 1445 (2005)
  3. Lee SH, Park JS, Koo CM, Lim BK, Kim SO, Macromol. Res., 16(3), 261 (2008)
  4. Hunt JH, Date RW, Timimi BA, Luckhurst GR, Bruce DW, J. Am. Chem. Soc., 123, 115 (2001)
  5. Kim BS, Suh KD, Kim B, Macromol. Res., 16(1), 76 (2008)
  6. Zhao S, Lee JH, Macromol. Res., 17, 256 (2009)
  7. Lee M, Yoo YS, J. Mater. Chem., 12, 2161 (2002)
  8. Hong DJ, Lee E, Jeong H, Lee JK, Zin WC, Nguyen TD, Glotzer SC, Lee M, Angew. Chem.-Int. Edit., 48, 1664 (2009)
  9. Jin LY, Ahn JH, Lee M, J. Am. Chem. Soc., 126(39), 12208 (2004)
  10. Sleytr UB, Messner P, Pum D, Sara M, Angew. Chem.-Int. Edit., 38, 1034 (1999)
  11. Zhong K, Chen T, Yin B, Jin LY, Macromol. Res., 17(4), 280 (2009)
  12. Jin LY, Bae J, Ahn JH, Lee M, Chem. Commun., 9, 1197 (2005)
  13. Hoeben FJM, Jonkheijm P, Meijer EW, Schenning APHJ, Chem. Rev., 105(4), 1491 (2005)
  14. Hill JP, Jin W, Kosake A, Fukushima T, Ichihara H, Shimomura T, Ito K, Hashizume T, Ishii N, Aida T, Science, 304, 1481 (2004)
  15. Ryu JH, Hong DJ, Lee M, Chem. Commun., 1043 (2008)
  16. Li ZB, Hillmyer MA, Lodge TP, Langmuir, 22(22), 9409 (2006)
  17. Guerin G, Raez J, Manners I, Winnik MA, Macromolecules, 38(18), 7819 (2005)
  18. Cho CS, Park IK, Nah JW, Akaike T, Macromol. Res., 11(1), 2 (2003)
  19. Moon KS, Lee E, Lee M, Chem. Commun., 3061 (2008)
  20. Jin LY, Bae J, Ryu JH, Lee M, Angew. Chem.-Int. Edit., 45, 650 (2005)
  21. Hue Q, Leon R, Petroff PM, Stucky GD, Science, 268(5215), 1324 (1995)
  22. Lee M, Cho BK, Kim H, Yoon JY, Zin WC, J. Am. Chem. Soc., 120(36), 9168 (1998)
  23. Lee M, Cho BK, Kim H, Zin WC, Angew. Chem.-Int. Edit., 37, 638 (1998)
  24. Lee M, Cho BK, Chem. Mater., 10, 1849 (1998)
  25. Lee M, Oh NK, Zin WC, Chem. Commun., 1787 (1996)
  26. Cho B, Chung YW, Lee M, Macromolecules, 38, 12061 (2005)
  27. Yoo YS, Choi JH, Song JH, Nam-Keun H, Zin WC, Park S, Chang TY, Lee M, J. Am. Chem. Soc., 126(20), 6294 (2004)
  28. Forster S, Plantenberg T, Angew. Chem.-Int. Edit., 41, 688 (2002)
  29. Zhang G, Jin W, Fukushima T, Kosaka A, Ishii N, Aida T, J. Am. Chem. Soc., 129(3), 719 (2007)
  30. Xu J, Zubarev ER, Angew. Chem.-Int. Edit., 43, 5491 (2004)
  31. Ornatska M, Peleshanko S, Genson KL, Rybak B, Bergman KN, Tsukruk VV, J. Am. Chem. Soc., 126(31), 9675 (2004)
  32. Schmidt M, Stockmayer WH, Macromolecules, 17, 509 (1984)
  33. Wang H, You W, Yu L, Wang HH, Chem. Eur. J., 10, 986 (2004)
  34. Kilbinger AFM, Schenning APHJ, Goldoni F, Feast WJ, Meijer EW, J. Am. Chem. Soc., 122(8), 1820 (2000)
  35. Tanatani A, Mio MJ, Moore JS, J. Am. Chem. Soc., 123(8), 1792 (2001)
  36. Miyaura N, Suzuki A, Chem. Rev., 95(7), 2457 (1995)
  37. Littke AF, Fu GC, Chem. Rev., 41, 4176 (2002)
  38. Uozumi Y, Nakai Y, Org. Lett., 4, 2997 (2002)
  39. Li L, Tedeshi C, Kurth DG, Mohwald H, Chem. Mater., 16, 570 (2004)