Synthesis, characterization and application of allyl phenol modified amberlite XAD-4 resin for preconcentration and determination of copper in water samples

Mahshid Nikpour Nezhati; Homayon Ahmad Panahi; Elham Moniri; Somayeh Rangbar Kelahrodi; Farah Assadian; Meghdad Karimi

Korean Journal of Chemical Engineering, Vol.27, No.4, 1269-1274, July, 2010

DOI10.1007/s11814-010-0174-y Export Citation

Synthesis, characterization and application of allyl phenol modified amberlite XAD-4 resin for preconcentration and determination of copper in water samples

Mahshid Nikpour Nezhati, Homayon Ahmad Panahi^†, Elham Moniri¹, Somayeh Rangbar Kelahrodi, Farah Assadian, and Meghdad Karimi

Department of Chemistry, Islamic Azad University, Central Tehran Branch, Iran
¹Department of Chemistry, Islamic Azad University, Varamin (Pishva) Branch, Iran

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A new chelating resin was prepared by coupling Amberlite XAD-4 with phenol through an azo spacer, then modified by allyl bromide and characterized (by elemental analysis and IR) and studied for preconcentration of Cu(II) using flame atomic absorption spectrometry (FAAS) for metal monitoring. The optimum pH value for sorption of the above mentioned metal ion was 4.5. The resin was subjected to chemical evaluation through batch binding and column chromatography of Cu(II). The chelating resin can be reused for 15 cycles of sorption-desorption without any significant change in sorption capacity. A recovery of 98% was obtained for the metal ion with 0.5M HNO3 as eluting agent. The equilibrium adsorption data of Cu(II) on modified resin were analyzed by Langmuir, Freundlich and Temkin models. Based on equilibrium adsorption data the Langmuir, Freundlich and Temkin constants were determined to be 0.061, 0.193 and 0.045 at pH 4.5 and 25 ℃. The method was applied for the copper determination from industrial waste water sample.

Keywords:Solid Phase Extraction;Amberlite XAD-4;Immobilization;Trace Element;Water Samples

[References]

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Camel V, Spectrochim. Acta Part B., 58, 1177 (2003)
Cekic SDD, Filik H, Apak R, Anal. Chim. Acta., 505, 15 (2004)
Dmitrienko SG, Sviridova OA, Pyatkova LN, Senyavin VM, Anal. Bioanal. Chem., 374, 361 (2002)
Gal PK, Patel S, Mishra BK, Talanta., 62, 1005 (2004)
Lemos VA, Baliza PX, Talanta., 67, 564 (2005)
Lemos VA, Santos JS, Baliza PX, Sep. Sci. Technol., 39(14), 3317 (2004)
Lemos VA, Baliza PX, Yamaki RT, Talanta., 61, 675 (2003)
Kumar M, Rathore DPS, Singh AK, Talanta., 51, 1187 (2000)
Narin I, Soylak M, Kayakirilmaz K, Elci L, Dogan M, Anal.Lett., 36, 641 (2003)
Prabhakaran D, Subramanian MS, Talanta., 59, 1227 (2003)
Tewari PK, Singh AK, Analyst., 125, 2350 (2000)
Tewari PK, Singh AK, Talanta., 56, 735 (2002)
Simpson NJK, Solid Phase Extraction, Principles, Techniques and Applications, 1th ed., Marcel Dekker Inc., New York (2000)
Saxena R, Singh AK, Rathore DPS, Analyst., 120, 403 (1995)
Tewari K, Singh AK, Analyst., 124, 1847 (1999)
Tewari PK, Singh AK, Talanta., 53, 823 (2001)
Guo Y, Din B, Liu Y, Chang X, Meng S, Tian M, Anal. Chim.Acta., 504, 319 (2004)
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Saxena R, Singh AK, Sambi SS, Anal. Chim. Acta., 295, 199 (1994)
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Dev K, Pathak R, Rao GN, Talanta., 48, 579 (1999)
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[Referenced By]

[1] Garg BS, Sharma RK, Bhojak N, Mittal S, Microchem. J., 61, 94 (1999)

[2] Camel V, Spectrochim. Acta Part B., 58, 1177 (2003)

[3] Cekic SDD, Filik H, Apak R, Anal. Chim. Acta., 505, 15 (2004)

[4] Dmitrienko SG, Sviridova OA, Pyatkova LN, Senyavin VM, Anal. Bioanal. Chem., 374, 361 (2002)

[5] Gal PK, Patel S, Mishra BK, Talanta., 62, 1005 (2004)

[6] Lemos VA, Baliza PX, Talanta., 67, 564 (2005)

[7] Lemos VA, Santos JS, Baliza PX, Sep. Sci. Technol., 39(14), 3317 (2004)

[8] Lemos VA, Baliza PX, Yamaki RT, Talanta., 61, 675 (2003)

[9] Kumar M, Rathore DPS, Singh AK, Talanta., 51, 1187 (2000)

[10] Narin I, Soylak M, Kayakirilmaz K, Elci L, Dogan M, Anal.Lett., 36, 641 (2003)

[11] Prabhakaran D, Subramanian MS, Talanta., 59, 1227 (2003)

[12] Tewari PK, Singh AK, Analyst., 125, 2350 (2000)

[13] Tewari PK, Singh AK, Talanta., 56, 735 (2002)

[14] Simpson NJK, Solid Phase Extraction, Principles, Techniques and Applications, 1th ed., Marcel Dekker Inc., New York (2000)

[15] Saxena R, Singh AK, Rathore DPS, Analyst., 120, 403 (1995)

[16] Tewari K, Singh AK, Analyst., 124, 1847 (1999)

[17] Tewari PK, Singh AK, Talanta., 53, 823 (2001)

[18] Guo Y, Din B, Liu Y, Chang X, Meng S, Tian M, Anal. Chim.Acta., 504, 319 (2004)

[19] Metilda P, Sanghamitra K, Mary Gladis J, Naidu GRK, Prasada Rao T, Talanta., 65, 192 (2005)

[20] Saxena R, Singh AK, Sambi SS, Anal. Chim. Acta., 295, 199 (1994)

[21] Lemos A, Baliza PX, Santos JS, Nunes LS, Sesus AA, Rocha ME, Talanta., 66, 174 (2005)

[22] Dev K, Pathak R, Rao GN, Talanta., 48, 579 (1999)

[23] Langmuir L, J. Am. Chem. Soc., 40, 1361 (1918)

[24] Hall KL, Eagleton LC, Acrivos A, Vermeulen T, Ind. Eng.Chem. Fundam., 5, 212 (1966)

[25] Freundlich HMA, J. Phys. Chem., 57, 385 (1906)