Primary study of volatiles composition of Rhodiola sachalinensis by using gas chromatography and mass spectrometry (GC/MS)

Yinzhe Jin; Dong Wha Park; Xifeng Li; Donghao Li; Kyung Ho Row

Korean Journal of Chemical Engineering, Vol.27, No.4, 1262-1268, July, 2010

DOI10.1007/s11814-010-0170-2 Export Citation

Primary study of volatiles composition of Rhodiola sachalinensis by using gas chromatography and mass spectrometry (GC/MS)

Yinzhe Jin^{1, 2}, Dong Wha Park^{2, 3}, Xifeng Li⁴, Donghao Li⁴, and Kyung Ho Row^{2, †}

¹College of Food Science and Technology, Shanghai Ocean University, 999 Hucheng Huan Road, Shanghai 201-306, China
²Department of Chemical Engineering, Inha University, 253 Yonghyun-dong, Nam-gu, Incheon 402-751, Korea
³Regional Innovation Center for Environmental Technology of Thermal Plasma (ETTP), Inha University, 253 Yonghyun-dong, Nam-gu, Incheon 402-751, Korea
⁴Analysis and Inspection Center, Yanbian Univerity, Park Road 977, Yanji City, Jilin Province, China

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To determine the volatile compounds in Rhodiola sachalinensis, hydro-distillation (HD) and headspace liquid-phase micro-extraction (HS-LPME) were used to extract 75 and 68 volatiles, respectively. Geraniol (24.73%), n-octanol (15.56%), and linalool (14.51%) were the most abundant essential oils detected in the HD samples, while geraniol (24.17%) and n-octanol (15.81%) were also detected at high levels in the HS-LPME samples. The main chemical classes of the essential oils were monoterpene alcohols in both the HD and HS-LPME samples at 59.02% and 37.64%, respectively. The O-heterocyclic (8.52%) and aromatic (5.92%) compounds were more abundant in the HS-LPME samples than in the HD samples.

Keywords:Volatiles;HD;HS-LPME;Rhodiola sachalinensis;GC/MS

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[Related Articles]

[1] Gyorgy Z, Tolonen A, Pakonen M, Neubauer P, Hohtola A, Plant Science., 166, 229 (2004)

[2] Li T, Xu G, Wu L, Sun C, Phytomedicine., 14(9), 601 (2007)

[3] Zhou G, Guan Y, Chen H, Ye J, J. Chromatogr. A., 1142, 236 (2007)

[4] Nakamura S, Li X, Matsuda H, Ninomiya K, Morikawa T, Yamaguti K, Yoshikawa M, Chem. Pharm. Bull., 55(10), 1505 (2007)

[5] Ma CY, Tang J, Wang H, Gu X , Tao G, Chromatographia., 67, 383 (2008)

[6] Mao Y, Li Y, Yao N, J. Pharm. Biomed. Anal., 45(3), 510 (2007)

[7] Nan JX, Jiang YZ, Park EJ, Ko G, Kim YC, Sohn DH, J. Ethnopharm., 84, 143 (2003)

[8] Zhang SQ, Bi HM, Liu CJ, Sep. Purif. Technol., 57(2), 277 (2007)

[9] Lee YW, Jin YZ, Row KH, Korean J. Chem. Eng., 23(2), 279 (2006)

[10] Burt S, Int. J. Food Microbiol., 94, 223 (2004)

[11] Jalali HM, Sereshti H, J. Chromatogr. A., 1160, 81 (2007)

[12] Grosso C, Ferraro V, Figueiredo AC, Barroso JG, Coelho JA, Palavra AM, Food Chemistry., 111, 197 (2008)

[13] Yamini Y, Khajeh M, Ghasemi E, Mirza M, Javidnia K, Food Chemistry., 108, 341 (2008)

[14] Safaralie A, Fatemi S, Sefidkon F, J. Chromatogr. A., 1180, 159 (2008)

[15] Pourmortazavi SM, Hajimirsadeghi SS, J. Chromatogr. A., 1163, 2 (2007)

[16] Bocevska M, Sovova H, J. Supercrit. Fluids, 40(3), 360 (2007)

[17] Paolini J, Leandri C, Desjobert JM, Barboni T, Costa J, J.Chromatogr. A., 1193, 37 (2008)

[18] Camara JS, Marques JC, Perestrelo RM, Rodrigues F, Oliveira L, Andrade P,Caldeira M, J. Chromatogr. A., 1150, 198 (2007)

[19] Don L, Deng C, Wang J, Shen X, Analytica Chimica Acta., 585, 76 (2007)

[20] Li N, Deng C, Li Y, Ye H, Zhang X, J. Chromatogr. A., 1133, 29 (2006)

[21] Lopez P, Huerga MA, Batlle R, Nerin C, Analytica Chimica Acta., 559, 97 (2006)

[22] Fakhari AR, Salehi P, Heydari R, Ebrahimi SN, Haddad PR, J. Chromatogr. A., 1098, 14 (2005)

[23] Adam M, Juklova M, Bajer T, Eisner A, Ventura K, J. Chromatogr. A., 1084, 2 (2005)

[24] Rohloff J, Phytochemistry., 59, 655 (2002)

[25] Lei Y, Nan P, Tsering T, Bai Z, Tian C, Zhong Y, Zeitschrift fur Naturforschung C., 58C, 161 (2003)

[26] Lei Y, Nan P, Tsering T, Wang L, Liu S, Zhong Y, Biochem.System Ecol., 32, 611 (2004)

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[28] Tsering T, Bai Z, Nan P, Tsering Q, Lei Y, Liu J, Wang L, Zhong Y, Chemistry of Natural Compounds., 43, 716 (2007)