This work is focused on the structural, morphological and textural modifications induced on zinc titanate high temperature desulfurizing sorbents by Al2O3 addition, thermal treatments and sulfurizing processes. ZnO-TiO2-Al2O3 type sorbents were obtained by dry and semi-wet mechanical blending of zinc oxide, titanium oxide and hydrated alumina, drying the intermediate product and by a final calcination at various temperatures. Depending on the initial ZnO:TiO2:Al2O3 molar ratio and final calcination temperatures (400800 degrees C) several mixed oxides may be formed: zinc titanates (Zn2TiO4 and Zn2Ti3O8), zinc aluminate (ZnAl2O4) and aluminium titanate (Al2TiO5). The presence of Al2O3 induces Structural and textural modifications, causes an improvement in pore structure and an increase in specific surface alleviating the, gas-solid interactions during the desulfurization-regeneration processes. The sulfurization process modifies the structural, morphological and textural characteristics of ZnO-TiO2-Al2O3 sorbents by reducing the zinc titanates and ZnS formation as main phase in the bulk of sorbent. (C) 2008 Elsevier B.V. All rights reserved.