Chemical absorption of carbon dioxide into phenyl glycidyl ether solution containing THA-CP-MS41 catalyst

Young-Son Choe; Kwang-Joong Oh; Min-Chul Kim; Sang-Wook Park

Korean Journal of Chemical Engineering, Vol.27, No.6, 1868-1875, November, 2010

DOI10.1007/s11814-010-0309-1 Export Citation

Chemical absorption of carbon dioxide into phenyl glycidyl ether solution containing THA-CP-MS41 catalyst

Young-Son Choe , Kwang-Joong Oh¹, Min-Chul Kim¹, and Sang-Wook Park^†

Division of Chemical and Biomolecular Engineering, Pusan National University, Busan 609-735, Korea
¹Division of Civil and Environmental Engineering, Pusan National University, Busan 609-735, Korea

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Carbon dioxide was absorbed into the phenyl glycidyl ether (PGE) solution within a range of 0-2.0 kmol/m3 in a stirred batch tank with a planar gas-liquid interface at 333-363 K and 101.3 kPa. Trihexylamine-immobilized on chloropropyl-functionalized MCM-41 (THA-CP-MS41) was used as a mesoporous catalyst, dispersed in organic liquid for the reaction between carbon dioxide and PGE. The measured absorption rates were analyzed to obtain the reaction kinetics of the consecutive chemical reactions which consisted of two steps using the mass transfer mechanism based on film theory. The overall reaction kinetics, analyzed with the pseudo-first-order reaction constant in the consecutive reaction model, was equivalent to the consecutive reaction kinetics. Effects of polar solvent, such as N, Ndimethylacetamide, N-methyl-2-pyrrolidinone, and dimethyl sulfoxide, on the reaction rate constants were observed using the solubility parameter of the solvent.

Keywords:Absorption;Carbon Dioxide;Phenyl Glycidyl Ether;Trihexylamine;MCM-41

[References]

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Nishikubo Y, Kato T, Sugimoto S, Tomoi M, Ishigaki S, Macromolecules, 23, 3406 (1990)
Kihara N, Endo T, Macromolecules, 25, 4824 (1992)
Nishikubo T, Kameyama A, Yamashida J, Tomoi M, Fukuda W, J. Polym. Sci., Part A, Polym. Chem., 31, 939 (1993)
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Starks CM, Liotta CL, Halpern M, Phase Transfer Catalysis, Chapmann & Hall, New York (1994)
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Kresge CT, Leonowicz ME, Roth WJ, Vartuli JC, Beck JS, Nature, 359, 710 (1992)
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Park SW, Lee JW, Stud. Surf. Sci. Catal., 159, 345 (2006)
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Park SW, Choi BS, Lee BD, Park DW, Kim SS, Sep. Sci. Technol., 41(5), 829 (2006)
Park SW, Choi BS, Park DW, Oh KJ, Lee JW, Green Chem., 9, 605 (2007)
Park SW, Choi BS, Park DW, Udayakumar S, Lee JW, Catal. Today, 131(1-4), 559 (2008)
Son YS, Park SW, Park DW, Oh KJ, Kim SS, Korean J. Chem. Eng., 26(3), 783 (2009)
Yu W, Astarita G, Savage DW, Chem. Eng. Sci., 40, 1585 (1985)
Kennard ML, Meisen A, J. Chem. Eng. Data, 29, 309 (1984)
Reid RC, Prausnitz JM, Sherwood TK, The properties of Gases and Liquid, McGraw-Hill Book Company, New York (1977)
Cussler EL, Diffusion, Cambridge University Press, New York (1984)
Carta G, Pigford RL, Ind. Eng. Chem. Fundam., 22, 329 (1983)
Herbrandson HF, Neufeld FB, J. Org. Chem., 31, 1140 (1966)
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[2] Weissermel K, Arpe H, Industrial Organic Chemistry; Wiley-VCH, Weinheim, New York (1997)

[3] Peppel WJ, Ind. Eng. Chem., 50, 767 (1958)

[4] Rokicki G, Makromol. Chem., 186, 331 (1985)

[5] Aida T, Inoue S, J. Am. Chem. Soc., 105, 1304 (1983)

[6] Nishikubo Y, Kato T, Sugimoto S, Tomoi M, Ishigaki S, Macromolecules, 23, 3406 (1990)

[7] Kihara N, Endo T, Macromolecules, 25, 4824 (1992)

[8] Nishikubo T, Kameyama A, Yamashida J, Tomoi M, Fukuda W, J. Polym. Sci., Part A, Polym. Chem., 31, 939 (1993)

[9] Nishikubo T, Kameyama A, Yamashita J, Fukumitsu T, Maejima C, Tomoi M, J. Polym. Sci. A: Polym. Chem., 33(7), 1011 (1995)

[10] Starks CM, Liotta CL, Halpern M, Phase Transfer Catalysis, Chapmann & Hall, New York (1994)

[11] Daraiswany LK, Sharma MM, Heterogeneous Reaction: Analysis, Example and Reactor Design, John Wiley & Sons, New York (1980)

[12] Kresge CT, Leonowicz ME, Roth WJ, Vartuli JC, Beck JS, Nature, 359, 710 (1992)

[13] Beck JS, Vartuli JC, Roth WJ, Leonowicz ME, Kresge CT, Schmitt KD, Chu CTW, Olson DH, Sheppard EW, McCullen SB, Higgins JB, Schlenker JL, J. Am. Chem. Soc., 114, 10834 (1992)

[14] Zhao DY, Feng JL, Huo QS, Melosh N, Fredrickson GH, Chmelka BF, Stucky GD, Science, 279(5350), 548 (1998)

[15] Bhaumik A, Tatsumi T, J. Catal., 189(1), 31 (2000)

[16] Burkett SL, Sim SD, Mann SJ, J. Chem. Soc., Chem. Commun., 1367 (1996)

[17] Lim MH, Blanford CF, Stein A, J. Am. Chem. Soc., 119(17), 4090 (1997)

[18] Fowler CE, Lebeau B, Mann S, J. Chem. Soc., Chem. Commun., 1825 (1998)

[19] Babonneau F, Leite L, Fontlupt S, J. Mater. Chem., 9, 175 (1999)

[20] Udayakumar S, Park SW, Park DW, Choi BS, Catal. Commun., 9, 1563 (2007)

[21] Park SW, Park DW, Kim TY, Park MY, Oh KJ, Catal. Today, 98(4), 493 (2004)

[22] Park SW, Lee JW, Stud. Surf. Sci. Catal., 159, 345 (2006)

[23] Park SW, Choi BS, Park DW, Kim SS, J. Ind. Eng. Chem., 11(4), 527 (2005)

[24] Park SW, Choi BS, Lee BD, Park DW, Kim SS, Sep. Sci. Technol., 41(5), 829 (2006)

[25] Park SW, Choi BS, Park DW, Oh KJ, Lee JW, Green Chem., 9, 605 (2007)

[26] Park SW, Choi BS, Park DW, Udayakumar S, Lee JW, Catal. Today, 131(1-4), 559 (2008)

[27] Son YS, Park SW, Park DW, Oh KJ, Kim SS, Korean J. Chem. Eng., 26(3), 783 (2009)

[28] Yu W, Astarita G, Savage DW, Chem. Eng. Sci., 40, 1585 (1985)

[29] Kennard ML, Meisen A, J. Chem. Eng. Data, 29, 309 (1984)

[30] Reid RC, Prausnitz JM, Sherwood TK, The properties of Gases and Liquid, McGraw-Hill Book Company, New York (1977)

[31] Cussler EL, Diffusion, Cambridge University Press, New York (1984)

[32] Carta G, Pigford RL, Ind. Eng. Chem. Fundam., 22, 329 (1983)

[33] Herbrandson HF, Neufeld FB, J. Org. Chem., 31, 1140 (1966)

[34] Brandrup J, Immergut EH, Polymer Handbook, Second Ed., John Wiley & Sons, New York (1975)

[35] Morrison RT, Boyd RN, Org. Chem., Fourth Ed., Allyn and Bacon, Inc, Toronto (1983)