Preparation and characterization of electrospun Ag/polyacrylonitrile composite nanofibers

Jie Bai; Qingbiao Yang; Shan Wang; Yaoxian Li

Korean Journal of Chemical Engineering, Vol.28, No.8, 1761-1763, August, 2011

DOI10.1007/s11814-011-0006-8 Export Citation

Preparation and characterization of electrospun Ag/polyacrylonitrile composite nanofibers

Jie Bai^{1, 2}, Qingbiao Yang¹, Shan Wang², and Yaoxian Li^{1, †}

¹Department of Chemistry, Jilin University, Changchun 130021, P. R. China
²Chemical Engineering College, Inner Mongolia University of Technology, Huhhote 010051, P. R. China

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Novel composite nanofibers consisting of Ag nanoparticles and polyacrylonitrile (PAN) were fabricated successfully. The Raman properties of these Ag/PAN nanofibers were studied at low temperatures, which showed good Raman characteristics. In the process, a PAN solutio containing Ag ions was directly electrospun to obtain nanofiber films containing Ag ions, and the Ag ions of resulting composite nanofibers were reduced to Ag nanoparticles in N2H5OH aqueous solution. Then, we treated Ag/PAN composite nanofibers at 100℃ , 200℃ , 400 and 600 ℃, respectively. The Ag/PAN nanocomposite film was characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) patterns and surface-enhanced Raman scattering (SERS) spectroscopy.

Keywords:Polyacrylonitrile (PAN);Electrospinning;Nanofibers;Ag Nanoparticles;Raman Spectroscopy

[References]

Reneker DH, Yarin AL, Fong H, Koombhongse S, J. Appl. Phys., 87, 4531 (2000)
Lee SW, Belcher AM, Nano Lett., 4, 387 (2004)
Formhals A, US Patent, 1,975,504 (1934)
Formhals A, US Patent, 2,077,373 (1937)
Chronakis IS, J. Mater. Process Technol., 167, 283 (2005)
He W, Ma ZW, Yong T, Teo WE, Ramakrishna S, Biomaterials., 26, 7606 (2005)
Wang A, Hsieh AJ, Rutledge GC, Polymer, 46(10), 3407 (2005)
Wang C, Yan EY, Huang ZH, Zhao Q, Xin Y, Macromol. Rapid Commun., 28(2), 205 (2007)
Son WK, Youk JH, Lee TS, Park WH, Macromol. Rapid Commun., 25(18), 1632 (2004)
Yang MX, Gracias DH, Jacobs PW, Somorjai GA, Langmuir, 14(6), 1458 (1998)
Bringley JF, Rajeswaran M, Olson LP, Liebert NM, J. Solid State Chem., 178, 3074 (2005)
Nickel U, Castell AZ, Poppl K, Schneider S, Langmuir, 16(23), 9087 (2000)
Ding LP, Fang Y, Appl. Surf. Sci., 253(9), 4450 (2007)
Si MZ, Kang YP, Zhang ZG, Appl. Surf. Sci., 255(11), 6007 (2009)
Podlipensky A, Abdolvand A, Seifert G, Graener H, Deparis O, Kazansky PG, J. Phys. Chem. B, 108(46), 17699 (2004)
Murakoshi K, Tanaka H, Sawai Y, Nakato Y, J. Phys. Chem. B, 106(12), 3041 (2002)
Xiao JP, Xie Y, Tang R, Chen M, Tian XB, Adv. Mater., 13(24), 1887 (2001)
Yang QB, Li DM, Hong YL, Li ZY, Wang C, Qiu SL, Wei Y, Synthetic Met., 137, 973 (2003)
Jin WJ, Jeon HJ, Kim JH, Youk JH, Synthetic Met., 157, 454 (2007)
Son WK, Youk JH, Park WH, Carbohyd Polymer., 65, 430 (2006)

[Referenced By]

[1] Reneker DH, Yarin AL, Fong H, Koombhongse S, J. Appl. Phys., 87, 4531 (2000)

[2] Lee SW, Belcher AM, Nano Lett., 4, 387 (2004)

[3] Formhals A, US Patent, 1,975,504 (1934)

[4] Formhals A, US Patent, 2,077,373 (1937)

[5] Chronakis IS, J. Mater. Process Technol., 167, 283 (2005)

[6] He W, Ma ZW, Yong T, Teo WE, Ramakrishna S, Biomaterials., 26, 7606 (2005)

[7] Wang A, Hsieh AJ, Rutledge GC, Polymer, 46(10), 3407 (2005)

[8] Wang C, Yan EY, Huang ZH, Zhao Q, Xin Y, Macromol. Rapid Commun., 28(2), 205 (2007)

[9] Son WK, Youk JH, Lee TS, Park WH, Macromol. Rapid Commun., 25(18), 1632 (2004)

[10] Yang MX, Gracias DH, Jacobs PW, Somorjai GA, Langmuir, 14(6), 1458 (1998)

[11] Bringley JF, Rajeswaran M, Olson LP, Liebert NM, J. Solid State Chem., 178, 3074 (2005)

[12] Nickel U, Castell AZ, Poppl K, Schneider S, Langmuir, 16(23), 9087 (2000)

[13] Ding LP, Fang Y, Appl. Surf. Sci., 253(9), 4450 (2007)

[14] Si MZ, Kang YP, Zhang ZG, Appl. Surf. Sci., 255(11), 6007 (2009)

[15] Podlipensky A, Abdolvand A, Seifert G, Graener H, Deparis O, Kazansky PG, J. Phys. Chem. B, 108(46), 17699 (2004)

[16] Murakoshi K, Tanaka H, Sawai Y, Nakato Y, J. Phys. Chem. B, 106(12), 3041 (2002)

[17] Xiao JP, Xie Y, Tang R, Chen M, Tian XB, Adv. Mater., 13(24), 1887 (2001)

[18] Yang QB, Li DM, Hong YL, Li ZY, Wang C, Qiu SL, Wei Y, Synthetic Met., 137, 973 (2003)

[19] Jin WJ, Jeon HJ, Kim JH, Youk JH, Synthetic Met., 157, 454 (2007)

[20] Son WK, Youk JH, Park WH, Carbohyd Polymer., 65, 430 (2006)