Isothermal vapor-liquid equilibria for the binary system of dimethyl ether (CH3OCH3)+methanol (CH3OH)

Seol A Kim; Joon Hyuk Yim; Hun-Soo Byun; Jong Sung Lim

Korean Journal of Chemical Engineering, Vol.28, No.12, 2324-2328, December, 2011

DOI10.1007/s11814-011-0108-3 Export Citation

Isothermal vapor-liquid equilibria for the binary system of dimethyl ether (CH3OCH3)+methanol (CH3OH)

Seol A Kim, Joon Hyuk Yim, Hun-Soo Byun¹, and Jong Sung Lim^†

Department of Chemical and Biomolecular Engineering, Sogang University, C.P.O. Box 1142, Seoul 100-611, Korea
¹School of Biotechnology and Chemical Engineering, Chonnam National University, Yeosu, Jeonnam 550-749, Korea

E-mail:

Isothermal vapor-liquid equilibrium data for the binary mixture of dimethyl ether (CH3OCH3)+methanol (CH3OH) were measured within the temperature range of 308.15-328.15 K. The data in the two-phase region were measured by using a circulation-type equilibrium apparatus in which both vapor and liquid phases are continuously recirculated. The experimental data were correlated with the Peng-Robinson equation of state (PR-EoS) using the Wong-Sandler mixing rules combined with the NRTL excess Gibbs free energy model. The values calculated by the PR-EOS with the W-S mixing rules show good agreement with our experimental data.

Keywords:Dimethyl Ether (CH3OCH3);Methanol (CH3OH);Vapor-liquid Equilibria (VLE);Peng-Robinson Equation of State (PR-EoS)

[References]

Ying W, Zhou LB, Energy Fuels, 21(3), 1454 (2007)
Rasmussen P, Teodorescu M, J. Chem. Eng. Data., 46, 640 (2001)
Dimethyl Ether Technology and Markets 07/08-S3 Report, Chem-Systems (2008)
Prasad PSS, Bae JW, Kang SH, Lee YJ, Jun KW, Fuel Process. Technol., 89(12), 1281 (2008)
Streett WB, Chang E, Calado JCG, J. Chem. Eng. Data., 27, 293 (1982)
Zheng DX, Wu XG, Cao W, Wang N, Chin. J. Chem. Eng., 14(5), 690 (2006)
Holldorff H, Knapp H, Fluid Phase Equilib., 40, 113 (1988)
Teodorecu M, Rasmussen P, J. Chem. Eng. Data., 46, 642 (2001)
Peng DY, Robinson DB, Ind. Eng. Chem. Fundam., 15, 59 (1976)
Wong DSH, Sandler SI, AIChE J., 38, 671 (1992)
Kim SA, Yoo KP, Lim JS, Korean J. Chem. Eng., 27(6), 1887 (2010)
Kim DY, Kim SJ, Yeo MK, Jung IG, Kang MS, Korean J. Chem. Eng., 26(1), 261 (2009)
Seong G, Lim JS, Byun HS, Korean J. Chem. Eng., 25, 1470 (2008)
Lim JS, Seong G, Roh HK, Lee BG, J. Chem. Eng. Data., 52, 2250 (2007)
Wong DSH, Orbey H, Sandler SI, Ind. Eng. Chem. Res., 31, 2033 (1992)
Renon H, Prausnitz JM, AIChE J., 14, 135 (1968)
Reid RC, Prausnitz JM, Poling BE, The Properties of Gases and Liquids (fourth edition), McGraw-Hill (1986)

[Referenced By]

[Related Articles]

[1] Ying W, Zhou LB, Energy Fuels, 21(3), 1454 (2007)

[2] Rasmussen P, Teodorescu M, J. Chem. Eng. Data., 46, 640 (2001)

[3] Dimethyl Ether Technology and Markets 07/08-S3 Report, Chem-Systems (2008)

[4] Prasad PSS, Bae JW, Kang SH, Lee YJ, Jun KW, Fuel Process. Technol., 89(12), 1281 (2008)

[5] Streett WB, Chang E, Calado JCG, J. Chem. Eng. Data., 27, 293 (1982)

[6] Zheng DX, Wu XG, Cao W, Wang N, Chin. J. Chem. Eng., 14(5), 690 (2006)

[7] Holldorff H, Knapp H, Fluid Phase Equilib., 40, 113 (1988)

[8] Teodorecu M, Rasmussen P, J. Chem. Eng. Data., 46, 642 (2001)

[9] Peng DY, Robinson DB, Ind. Eng. Chem. Fundam., 15, 59 (1976)

[10] Wong DSH, Sandler SI, AIChE J., 38, 671 (1992)

[11] Kim SA, Yoo KP, Lim JS, Korean J. Chem. Eng., 27(6), 1887 (2010)

[12] Kim DY, Kim SJ, Yeo MK, Jung IG, Kang MS, Korean J. Chem. Eng., 26(1), 261 (2009)

[13] Seong G, Lim JS, Byun HS, Korean J. Chem. Eng., 25, 1470 (2008)

[14] Lim JS, Seong G, Roh HK, Lee BG, J. Chem. Eng. Data., 52, 2250 (2007)

[15] Wong DSH, Orbey H, Sandler SI, Ind. Eng. Chem. Res., 31, 2033 (1992)

[16] Renon H, Prausnitz JM, AIChE J., 14, 135 (1968)

[17] Reid RC, Prausnitz JM, Poling BE, The Properties of Gases and Liquids (fourth edition), McGraw-Hill (1986)