Solubility of hinokitiol in supercritical fluids; measurement and correlation

Junhyuk Lim; Hwayong Kim; Hye Kyung Cho; Moon Sam Shin

Korean Journal of Chemical Engineering, Vol.28, No.12, 2319-2323, December, 2011

DOI10.1007/s11814-011-0112-7 Export Citation

Solubility of hinokitiol in supercritical fluids; measurement and correlation

Junhyuk Lim, Hwayong Kim , Hye Kyung Cho¹, and Moon Sam Shin^{1, †}

School of Chemical & Biological Engineering, Seoul National University, Seoul 151-744, Korea
¹Department of Dermatological Health Management, Eulji University, 212 Yangji-dong, Sujeong-gu, Seongnam-si, Gyeonggi-do 461-713, Korea

E-mail:

Supercritical fluid technology has been an alternative for purification and separation of biological compounds in cosmetic, food, and pharmaceutical products. Solubility information of biological compounds in supercritical fluids is essential for choosing a supercritical fluid processes. The equilibrium solubility of hinokitiol was measured in supercritical carbon dioxide and ethane with a static method in the pressure range from 8 to 40MPa and at temperatures equal to 313.2, 323.2 and 333.2 K. The experimental data were correlated well by Peng-Robinson equation of state and quasi-chemical nonrandom lattice fluid model.

Keywords:Supercritical Fluids;Hinokitiol;Carbon Dioxide;Ethane;Solubility

[References]

Byeon SE, Lee YG, Kim JC, Han JG, Lee HY, Cho JY, Planta Med., 74, 828 (2008)
Komaki N, Watanabe T, Ogasawara A, Sato N, Mikami T, Matsumoto T, Biol. Pharm. Bull., 31, 735 (2008)
Manter KD, Kelsey RG, Karchesy JJ, J. Chem. Ecol., 33, 2133 (2007)
Murakami K, Ohara Y, Haneda M, Tsubouchi R, Yoshino M, Basic Clin. Pharmacol. Toxicol., 97, 392 (2005)
Liu S, Yamauchi H, Cancer Lett., 286, 240 (2009)
Kim DS, Park SH, Kwon SB, Li K, Youn SW, Park KC, Arch. Pharm. Res., 27, 334 (2004)
Baba T, Nakano H, Tamai K, Sawamura D, Hanada K, Hashimoto I, Arima Y, J. Invest. Dermatol., 110, 24 (1998)
Teja AS, Eckert CA, Ind. Eng. Chem. Res., 39, 4442 (2000)
Rincon J, Martinez F, Rodriguez L, Ancillo V, J. Supercrit. Fluids, 56(1), 72 (2011)
McHugh MA, Seckner AJ, Yogan TJ, Ind. Eng. Chem. Fundam., 23, 493 (1984)
Kurnik RT, Holla SJ, Reid RC, J. Chem. Eng. Data., 26, 47 (1981)
Schafer K, Baumann W, Fres. Z. Anal. Chem., 332, 122 (1988)
Weinstein RD, Hanlon WH, Donohue JP, Simeone M, Rozich A, Muske KR, J. Chem. Eng. Data., 52, 256 (2007)
Brennecke JF, Eckert CA, AIChE J., 35, 1409 (1989)
Skerget M, Novak-Pintaric Z, Knez Z, Kravanja Z, Fluid Phase Equilib., 203(1-2), 111 (2002)
Cheng JS, Tang M, Chen YP, Fluid Phase Equilib., 194, 483 (2002)
Nicolas C, Neau E, Meradji S, Raspo I, Fluid Phase Equilib., 232(1-2), 219 (2005)
Shin MS, Kim H, Fluid Phase Equilib., 246(1-2), 79 (2006)
Shin MS, Kim H, Fluid Phase Equilib., 256(1-2), 27 (2007)
Shin MS, Kim H, J. Chem. Thermodyn., 40(7), 1110 (2008)
Shin MS, Lee JH, Kim H, Fluid Phase Equilib., 272(1-2), 42 (2008)
Shin MS, Kim H, Fluid Phase Equilib., 270(1-2), 45 (2008)
Shin MS, Kim H, Clean Technol., 14(3), 153 (2008)
Park CI, Shin MS, Kim H, J. Chem. Thermodyn., 41(1), 30 (2009)
Peng DY, Robinson DB, Ind. Eng. Chem. Fundam., 15, 59 (1976)
Bae W, Kwon SY, Byun HS, Kim HY, J. Supercrit. Fluids, 30(2), 127 (2004)
Stein SE, Brown RL, J. Chem. Inf. Comput. Sci., 34, 581 (1994)
Lyman WJ, Reehl WF, Rosenblatt DH, Handbook of Chemical and Physical Property Estimation Methods: Environmental Behavior of Organic Compounds, American Chemical Society, Washington, D.C. (1990)
Fedors RF, Polym. Eng. Sci., 14, 147 (1974)
Kang J, Yoo KP, Kim H, Lee J, Yang D, Lee CS, Int. J. Thermophys., 22, 487 (2001)

[Related Articles]

[1] Byeon SE, Lee YG, Kim JC, Han JG, Lee HY, Cho JY, Planta Med., 74, 828 (2008)

[2] Komaki N, Watanabe T, Ogasawara A, Sato N, Mikami T, Matsumoto T, Biol. Pharm. Bull., 31, 735 (2008)

[3] Manter KD, Kelsey RG, Karchesy JJ, J. Chem. Ecol., 33, 2133 (2007)

[4] Murakami K, Ohara Y, Haneda M, Tsubouchi R, Yoshino M, Basic Clin. Pharmacol. Toxicol., 97, 392 (2005)

[5] Liu S, Yamauchi H, Cancer Lett., 286, 240 (2009)

[6] Kim DS, Park SH, Kwon SB, Li K, Youn SW, Park KC, Arch. Pharm. Res., 27, 334 (2004)

[7] Baba T, Nakano H, Tamai K, Sawamura D, Hanada K, Hashimoto I, Arima Y, J. Invest. Dermatol., 110, 24 (1998)

[8] Teja AS, Eckert CA, Ind. Eng. Chem. Res., 39, 4442 (2000)

[9] Rincon J, Martinez F, Rodriguez L, Ancillo V, J. Supercrit. Fluids, 56(1), 72 (2011)

[10] McHugh MA, Seckner AJ, Yogan TJ, Ind. Eng. Chem. Fundam., 23, 493 (1984)

[11] Kurnik RT, Holla SJ, Reid RC, J. Chem. Eng. Data., 26, 47 (1981)

[12] Schafer K, Baumann W, Fres. Z. Anal. Chem., 332, 122 (1988)

[13] Weinstein RD, Hanlon WH, Donohue JP, Simeone M, Rozich A, Muske KR, J. Chem. Eng. Data., 52, 256 (2007)

[14] Brennecke JF, Eckert CA, AIChE J., 35, 1409 (1989)

[15] Skerget M, Novak-Pintaric Z, Knez Z, Kravanja Z, Fluid Phase Equilib., 203(1-2), 111 (2002)

[16] Cheng JS, Tang M, Chen YP, Fluid Phase Equilib., 194, 483 (2002)

[17] Nicolas C, Neau E, Meradji S, Raspo I, Fluid Phase Equilib., 232(1-2), 219 (2005)

[18] Shin MS, Kim H, Fluid Phase Equilib., 246(1-2), 79 (2006)

[19] Shin MS, Kim H, Fluid Phase Equilib., 256(1-2), 27 (2007)

[20] Shin MS, Kim H, J. Chem. Thermodyn., 40(7), 1110 (2008)

[21] Shin MS, Lee JH, Kim H, Fluid Phase Equilib., 272(1-2), 42 (2008)

[22] Shin MS, Kim H, Fluid Phase Equilib., 270(1-2), 45 (2008)

[23] Shin MS, Kim H, Clean Technol., 14(3), 153 (2008)

[24] Park CI, Shin MS, Kim H, J. Chem. Thermodyn., 41(1), 30 (2009)

[25] Peng DY, Robinson DB, Ind. Eng. Chem. Fundam., 15, 59 (1976)

[26] Bae W, Kwon SY, Byun HS, Kim HY, J. Supercrit. Fluids, 30(2), 127 (2004)

[27] Stein SE, Brown RL, J. Chem. Inf. Comput. Sci., 34, 581 (1994)

[28] Lyman WJ, Reehl WF, Rosenblatt DH, Handbook of Chemical and Physical Property Estimation Methods: Environmental Behavior of Organic Compounds, American Chemical Society, Washington, D.C. (1990)

[29] Fedors RF, Polym. Eng. Sci., 14, 147 (1974)

[30] Kang J, Yoo KP, Kim H, Lee J, Yang D, Lee CS, Int. J. Thermophys., 22, 487 (2001)