화학공학소재연구정보센터
Applied Surface Science, Vol.257, No.20, 8465-8468, 2011
Enhancement of saturation magnetization in Cr-ion implanted silicon by high temperature annealing
Magnetic properties and microstructure of Cr-implanted Si have been investigated by alternating gradient magnetometer (AGM), superconducting quantum interference device (SQUID) magnetometer, and transmission electron microscopy (TEM). p-Type (1 0 0) Si wafers were implanted at 200 keV at room temperature with a dosage of 1 x 10(16) cm(-2) Cr ions and then annealed at 600-900 degrees C for 5 min. The effect of annealing on the structure and magnetic properties of Cr-implanted Si is studied. The as-implanted sample shows a square M-H loop at low temperature. Magnetic signal becomes weaker after short time annealing of the as-implanted sample at 600 degrees C, 700 degrees C, and 800 degrees C. However, the 900 degrees C annealed sample exhibits large saturation magnetization at room temperature. TEM images reveal that the implanting process caused amorphization of Si, while annealing at 900 degrees C led to partial recovery of the crystal. The enhancement of saturation magnetization can be explained by the redistribution and accumulation of Cr atoms in the vacancy-rich region of Si during annealing. (C) 2011 Elsevier B. V. All rights reserved.