Nanoporous Thin Films of Fully Alicyclic Polyimides

Hwan-Chul Yu; S. Vijay Kumar; Young-Kyu Song; Jiyoung Choi; Kazuaki Kudo; Joong-Gon Kim; Se-Young Oh; Chan-Moon Chung

Macromolecular Research, Vol.19, No.12, 1272-1277, December, 2011

DOI10.1007/s13233-011-1216-y Export Citation

Nanoporous Thin Films of Fully Alicyclic Polyimides

Hwan-Chul Yu, S. Vijay Kumar, Young-Kyu Song, Jiyoung Choi¹, Kazuaki Kudo¹, Joong-Gon Kim², Se-Young Oh³, and Chan-Moon Chung^†

Department of Chemistry, Yonsei University, Gangwon, 220-710, Korea
¹Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo, 153-8305, Japan
²Hanwha Chemical R&D Center, Daejeon, 305-345, Korea
³Department of Chemical and Biomolecular Engineering, Sogang University, Seoul, 121-742, Korea

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Nanopore generation could be accomplished in thin films of fully alicyclic polyimides derived from an alicyclic dianhydride and diamines. A silylation method for the alicyclic diamines was used to synthesize high molecular weight alicyclic polyimides. Triblock copolyimides were prepared using N-silylated alicyclic diamines, alicyclic dianhydride, and a thermally labile polymer. Nanoporous films of fully alicyclic polyimides were prepared through heating of the copolyimide films to induce thermal degradation of the labile block.

Keywords:nanoporous film;fully alicyclic polyimide;silylation;triblock copolyimide.

[References]

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Maier G, Prog. Polym. Sci., 26, 3 (2001)
Mathews AS, Kim I, Ha CS, Macromol. Res., 15(2), 114 (2007)
Zhao XJ, Liu JG, Li HS, Fan L, Yang SY, J. Appl. Polym. Sci., 111(5), 2210 (2009)
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Liaw DJ, Huang CC, Chen WH, Macromol. Chem.Phys., 207, 434 (2006)
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Kato J, Seo A, Shiraishi S, Macromolecules, 32(20), 6400 (1999)
Li J, Kudo K, Shiraishi S, Macromol. Rapid Commun., 21(16), 1166 (2000)
Li J, Kato J, Kudo K, Shiraishi S, Macromol. Chem.Phys., 201, 2289 (2000)
Watanabe Y, Sakai Y, Shibasaki Y, Ando S, Ueda M, Oishi Y, Mori K, Macromolecules, 35(6), 2277 (2002)
Mathews AS, Kim I, Ha CS, J. Polym. Sci. A: Polym. Chem., 44(18), 5254 (2006)
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Fu GD, Wang WC, Li S, Kang ET, Neoh KG, Tseng WT, Liaw DJ, J. Mater. Chem., 13, 2150 (2003)
Carter KR, Dipietro RA, Sanchez MI, Swanson SA, Chem. Mater., 13, 213 (2001)
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Chung CM, Lee JH, Cho SY, Kim JG, Moon SY, J. Appl. Polym. Sci., 101(1), 532 (2006)
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Hadjichristidis N, Pispas S, Floudas G, Block Copolymers: Synthetic Strategies, Physical Properties, and Applications, John Wiley & Sons, New Jersey (2003)
Seino H, Sasaki T, Mochizuki A, Ueda M, High Perform. Polym., 11, 255 (1999)
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Takeichi T, Yamazaki Y, Zuo M, Ito A, Matsumoto A, Inagaki M, Carbon., 39, 257 (2001)

[Related Articles]

[1] Ghosh KL, Mittal KL, Eds., Polyimides: Fundamentals and Applications, Marcel Dekker, New York (1996)

[2] Maier G, Prog. Polym. Sci., 26, 3 (2001)

[3] Mathews AS, Kim I, Ha CS, Macromol. Res., 15(2), 114 (2007)

[4] Zhao XJ, Liu JG, Li HS, Fan L, Yang SY, J. Appl. Polym. Sci., 111(5), 2210 (2009)

[5] Ge Z, Fan L, Yang SY, Eur. Polym. J., 44, 1252 (2008)

[6] Liaw DJ, Chang FC, J. Polym. Sci. A: Polym. Chem., 42(22), 5766 (2004)

[7] Liaw DJ, Huang CC, Chen WH, Macromol. Chem.Phys., 207, 434 (2006)

[8] Liu JG, He MH, Zhou HW, Qian ZG, Wang FS, Yang SY, J. Polym. Sci. Part A: Polym. Chem., 40, 110 (2001)

[9] Matsumoto T, Macromolecules, 32(15), 4933 (1999)

[10] Kato J, Seo A, Shiraishi S, Macromolecules, 32(20), 6400 (1999)

[11] Li J, Kudo K, Shiraishi S, Macromol. Rapid Commun., 21(16), 1166 (2000)

[12] Li J, Kato J, Kudo K, Shiraishi S, Macromol. Chem.Phys., 201, 2289 (2000)

[13] Watanabe Y, Sakai Y, Shibasaki Y, Ando S, Ueda M, Oishi Y, Mori K, Macromolecules, 35(6), 2277 (2002)

[14] Mathews AS, Kim I, Ha CS, J. Polym. Sci. A: Polym. Chem., 44(18), 5254 (2006)

[15] Chern YT, Shiue HC, Chem. Mater., 10, 210 (1998)

[16] Goto K, Akiike T, Inoue Y, Matsubara M, Macromol.Symp., 199, 321 (2003)

[17] Hedrick JL, Carter KR, Richter R, Miller RD, Russell TP, Flores V, Meccereyes D, Dubois P, Jerome R, Chem.Mater., 10, 39 (1998)

[18] Hedrick JL, Russell TP, Sanchez M, Dipietro R, Swanson S, Mecerreyes D, Jerome R, Macromolecules, 29(10), 3642 (1996)

[19] Fu GD, Wang WC, Li S, Kang ET, Neoh KG, Tseng WT, Liaw DJ, J. Mater. Chem., 13, 2150 (2003)

[20] Carter KR, Dipietro RA, Sanchez MI, Swanson SA, Chem. Mater., 13, 213 (2001)

[21] Cho SY, Lee CH, Oh SY, Chung CM, Ultramicroscopy., 108, 1220 (2008)

[22] Chung CM, Lee JH, Cho SY, Kim JG, Moon SY, J. Appl. Polym. Sci., 101(1), 532 (2006)

[23] Oishi Y, Onodera S, Oravec J, Mori K, Ando S, Terui Y, Maeda K, J. Photopolym. Sci. Technol., 16, 263 (2003)

[24] Kumar SV, Yu HC, Choi J, Kudo K, Jang YH, Chung CM, J. Polym. Res., 18, 1111 (2011)

[25] Hadjichristidis N, Pispas S, Floudas G, Block Copolymers: Synthetic Strategies, Physical Properties, and Applications, John Wiley & Sons, New Jersey (2003)

[26] Seino H, Sasaki T, Mochizuki A, Ueda M, High Perform. Polym., 11, 255 (1999)

[27] Takeichi T, Yamazaki Y, Ito A, Zuo M, J. Photopolym.Sci. Technol., 12, 203 (1999)

[28] Takeichi T, Yamazaki Y, Zuo M, Ito A, Matsumoto A, Inagaki M, Carbon., 39, 257 (2001)