Fractionation of Poly(dimethyl siloxane) by Interaction Chromatography

Heungyeal Choi; Kyuhyun Im; Taihyun Chang

Macromolecular Research, Vol.20, No.1, 101-105, January, 2012

DOI10.1007/s13233-012-0006-5 Export Citation

Fractionation of Poly(dimethyl siloxane) by Interaction Chromatography

Heungyeal Choi, Kyuhyun Im, and Taihyun Chang^†

Department of Chemistry and Division of Advanced Materials Science, Pohang University of Science and Technology, Gyeongbuk, 790-784, Korea

E-mail:

Poly(dimethyl siloxane) (PDMS) was characterized by interaction chromatography using C4-bonded silica and a mixture of THF/CH3OH as the stationary phase and the mobile phase, respectively. Under the separation condition, a commercial PDMS with broad molecular weight distribution was successfully fractionated according to molecular weight into fractions with a very narrow molecular weight distribution. The IC separation could be applied to more rigorous characterization of PDMS, modified PDMS, and block copolymer-containing PDMS.

Keywords:poly(dimethylsiloxane);interaction chromatography;temperature gradient interaction chromatography(TGIC).

[References]

Barth HG, Mays JW, Modern Methods of Polymer Characterization, John Wiley & Sons, New York (1991)
Mori S, Barth HG, Size Exclusion Chromatography, Springer-Verlag, New York (1999)
Striegel AM, Yau WW, Kirkland JJ, Bly DD, Modern Size-Exclusion Liquid Chromatography: Practice of Gel Permeation and Gel Filtration Chromatography, 2nd ed., John Wiley & Sons, Hoboken, New Jersey (2009)
Pasch H, Trathnigg B, HPLC of Polymers, Springer-Verlag, Berlin (1997)
Chang T, Adv. Polym. Sci., 163, 1 (2003)
Lee W, Lee H, Cha J, Chang T, Hanley KJ, Lodge TP, Macromolecules, 33(14), 5111 (2000)
Lee HC, Chang TY, Polymer, 37(25), 5747 (1996)
Lee W, Lee HC, Park T, Chang T, Chae KH, Macromol.Chem. Phys., 201, 320 (2000)
Lee W, Lee HC, Chang TY, Kim SB, Macromolecules, 31(2), 344 (1998)
Cho D, Park S, Hong J, Chang T, J. Chromatogr. A., 986, 191 (2003)
Park S, Ko C, Choi H, Kwon K, Chang T, J. Chromatogr.A., 1123, 22 (2006)
Park S, Chang T, Macromolecules, 39(9), 3466 (2006)
Park HW, Jung J, Chang T, Macromol. Res., 17(6), 365 (2009)
Jones RG, Ando W, Chojnowski J, Silicon-Containing Polymers: The Science and Technology of Their Synthesis and Applications, Kluwer, Dordrecht (2000)
Im K, Park HW, Kim Y, Chang T, Macromol. Res., 16(6), 544 (2008)
Park S, Cho D, Ryu J, Kwon K, Chang T, Park J, J.Chromatogr. A., 958, 183 (2002)
Kruger RP, Much H, Schulz G, Rikowski E, Monatshefte fur Chemie., 130, 163 (1999)
Sinha P, Malik MI, Bayley G, Mallon P, Pasch H, 5th International Symposium on the Separation and Chracterization of Natural and Synthetic Macromolecules, Rhone Congress Centre, Amstredam (2011)
Chang T, J. Polym. Sci. B: Polym. Phys., 43(13), 1591 (2005)
Ryu J, Chang T, Anal. Chem., 77, 6347 (2005)

[1] Barth HG, Mays JW, Modern Methods of Polymer Characterization, John Wiley & Sons, New York (1991)

[2] Mori S, Barth HG, Size Exclusion Chromatography, Springer-Verlag, New York (1999)

[3] Striegel AM, Yau WW, Kirkland JJ, Bly DD, Modern Size-Exclusion Liquid Chromatography: Practice of Gel Permeation and Gel Filtration Chromatography, 2nd ed., John Wiley & Sons, Hoboken, New Jersey (2009)

[4] Pasch H, Trathnigg B, HPLC of Polymers, Springer-Verlag, Berlin (1997)

[5] Chang T, Adv. Polym. Sci., 163, 1 (2003)

[6] Lee W, Lee H, Cha J, Chang T, Hanley KJ, Lodge TP, Macromolecules, 33(14), 5111 (2000)

[7] Lee HC, Chang TY, Polymer, 37(25), 5747 (1996)

[8] Lee W, Lee HC, Park T, Chang T, Chae KH, Macromol.Chem. Phys., 201, 320 (2000)

[9] Lee W, Lee HC, Chang TY, Kim SB, Macromolecules, 31(2), 344 (1998)

[10] Cho D, Park S, Hong J, Chang T, J. Chromatogr. A., 986, 191 (2003)

[11] Park S, Ko C, Choi H, Kwon K, Chang T, J. Chromatogr.A., 1123, 22 (2006)

[12] Park S, Chang T, Macromolecules, 39(9), 3466 (2006)

[13] Park HW, Jung J, Chang T, Macromol. Res., 17(6), 365 (2009)

[14] Jones RG, Ando W, Chojnowski J, Silicon-Containing Polymers: The Science and Technology of Their Synthesis and Applications, Kluwer, Dordrecht (2000)

[15] Im K, Park HW, Kim Y, Chang T, Macromol. Res., 16(6), 544 (2008)

[16] Park S, Cho D, Ryu J, Kwon K, Chang T, Park J, J.Chromatogr. A., 958, 183 (2002)

[17] Kruger RP, Much H, Schulz G, Rikowski E, Monatshefte fur Chemie., 130, 163 (1999)

[18] Sinha P, Malik MI, Bayley G, Mallon P, Pasch H, 5th International Symposium on the Separation and Chracterization of Natural and Synthetic Macromolecules, Rhone Congress Centre, Amstredam (2011)

[19] Chang T, J. Polym. Sci. B: Polym. Phys., 43(13), 1591 (2005)

[20] Ryu J, Chang T, Anal. Chem., 77, 6347 (2005)