화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Applied Chemistry for Engineering, Vol.23, No.3, 271-278, June, 2012
Export Citation
산화 아연 나노 입자로 도포된 마이카의 합성 및 특성 규명
Synthesis and Characterization of Mica Coated with Zinc Oxide Nanoparticles
길현석, 김용호, 박민영, 이석우†
  • 공주대학교 화학과 및 그린홈에너지기술연구소
Hyun Suk Kil, Young Ho Kim, Minyoung Park, and Seog Woo Rhee†
  • Department of Chemistry and Green Home Energy Technology Research Center, Kongju National University, Kongju 314-701, Korea
E-mail:
초록
본 연구에서는 마이카와 산화 아연을 이용하여 복합 재료를 제조하고, 이를 자외선 차단 크림에 응용하는 연구를 수행하였다. 먼저 마이카와 산화 아연을 각각 3-aminopropyltrimethoxysilane (APTMS)으로 처리하여 표면에 아민기를 생성시켰다. 아민기가 붙은 마이카를 1,4-phenylenediisothiocyanate (PDC)와 반응시켜 표면에 -N=C=S 작용기를 활성화시킨 후, 아민기가 붙어있는 산화 아연과 결합시켜 산화 아연으로 덮인 마이카 복합 재료를 합성하였다. 원소 분석, EDS 분석, 열 중량 분석, SEM 이미지 분석, 형광 이미지 분석, 제타 전위 측정, X-선 회절 분석, DRS UV/Vis 분석을 통하여 고체 생성물의 특성을 규명하였다. 최종적으로 표준 프로토콜로 제조된 자외선 차단 크림의 파장에 따른 투과도를 280∼400 nm 범위에서 측정하여 자외선 차단 효과를 확인하였다.
In this work, we have prepared the nanocomposite by the reaction of mica and zinc oxide, and investigated the application of nanocomposite to UV protecting creams. Mica treated with 3-aminopropyltrimethoxysilane (APTMS) reacted with 1,4-phenylenediisothiocyanate (PDC) to give -N=C=S functionalized surface, which was further reacted with zinc oxides coated with APTMS to give mica-zinc oxide nanocomposites. The composites were characterized by EA, EDS, TGA, SEM, zeta potential measurement, powder XRD, and DRS UV/Vis analyses. Finally, we measured transmittances of ultraviolet protection creams manufactured by using mica composite covered with zinc oxides in the range of 280∼400 nm. The nanocomposites developed in this work might be applicable as inorganic hybrid materials for UV protecting creams.
Keywords:sun protection agent;ZnO;mica;nano composite;treatment of surface
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