화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2011년 가을 (10/26 ~ 10/28, 송도컨벤시아)
권호 17권 2호, p.1567
발표분야 에너지
제목 Study on the Applicability of Gas-Solid Reaction Models in the Gasification of Inner Mongolian Lignite with CO2 in the presence Alkali Metals and Transition Metal Salts
초록 Catalytic gasification of Inner Mongolian lignite with CO2 was investigated in a thermogravimetric analyzer at 600C-900C at 5% to 15% wt loading via physical mixing. Catalysts used were K2CO3, Na2CO3, K2SO4 and FeSO4. In this study, the (1) homogeneous (HM), (2) shrinking core (SCM), (3) random pore (RPM), (4) modified (MVM) and (5) extended modified volumetric models (EMVM) were evaluated and goodness of fit for the conversion behavior was measured from the root mean square deviation, R2. In most catalytic gasification runs, the RPM, MVM and EMVM showed goodness of fit and the EMVM approaches the MVM at higher temperatures. This study further confirms the applicability of EMVM for high-temperature uncatalyzed gasification (Wu et al, 2009) and further suggests its applicability to catalyzed gasification as well.
저자 Vergel Bungay1, 김경욱1, 송병호1, 김상돈2, 손정민3, 심현민4, 김용준4, 김규태4, 박삼룡4, 임영일5
소속 1군산대, 2KAIST, 3전북대, 4SK Energy, 5한경대
키워드 Gasification; Lignite; Catalytic
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