| 학회 |
한국화학공학회 |
| 학술대회 |
2005년 가을 (10/21 ~ 10/22, 인하대학교) |
| 권호 |
11권 2호, p.2634 |
| 발표분야 |
촉매 및 반응공학 |
| 제목 |
The H2 production from the hexadecane partial oxidation on Rh-loading catalysts |
| 초록 |
The diesel engine has a good fuel economy and high durability. However, the emission of NOx is plenty, resulted in the occurrence of air pollution. So NOx removal is presently receiving considerable research attention. In recent reviews, the synthesis gas and olefins produced from the diesel fuel partial oxidation devices were directly injected into a de-NOx catalyst system. Therefore in this study, we have an attempt to produce the synthesis gas by a partial oxidation of hexadecane over Rh catalysts. The partial oxidation efficiency increased with an increase of reaction temperature untill 800℃; The best conversion of hexadecane was obtained at above 700℃ and the best selectivities of CO and H2 were exhibited at 800℃ on all catalysts. Particularly, partial oxidation of hexadecane was improved in the order of Al2O3< Rh/Al2O3< Ce-Zr-LaOx< Rh-Ce-Zr-LaO |
| 저자 |
조자경, 김철민, 김준우, 김동진, 강미숙, 정석진
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| 소속 |
경희대 |
| 키워드 |
Hydrogen; Rh; Hexadecane; de-NOx
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| E-Mail |
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| 원문파일 |
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