화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2005년 가을 (10/21 ~ 10/22, 인하대학교)
권호 11권 2호, p.2451
발표분야 이동현상
제목 Effects of Thermo-Solutal Convection during the Crystal Growth Processes of Mercurous Chloride (Hg2Cl2)
초록 The effects of convection on the crystal growth rates of mercurous chloride (Hg2Cl2) are investigated for convective-diffusive conditions and purely diffusion conditions achievable in low gravity environments under a nonlinear thermal profile. For 4 £ MB £ 472.086, the solute driven convection (solutal Grashof number Grs = 1.72 x 105) due to the disparity in the molecular weights of the component A (Hg2Cl2) and B (argon:Ar) is stronger than the thermally-driven convection (thermal Grashof number Grt = 1.05 x 104), for an aspect ratio (transport length-to-width) of 5, total pressure of 35,455 Pascal, Pr = 0.667, Le = 0.47, Pe = 3.57, Cv = 1.029.With the temperature humps, there were found to be in undersaturations along the transport path for convective-diffusive processes ranging from DAB = 0.0584 cm2/s to 0.584 cm2/s, in axial positions from 0 to 7.5 cm. The diffusion mode is predominant over convection for gravity levels less than 0.1 g0 for the horizontally-oriented configuration.
저자 이대수
소속 한남대
키워드 mercurous chloride; solute driven convection; and physical vapor transport
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