화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.66, 248-253, October, 2018
DOI10.1016/j.jiec.2018.05.036  Export Citation
Facile fabrication of porous Sn-based catalysts for electrochemical CO2 reduction to HCOOH and syngas
Hyenki Kim, Hyunju Lee, Taeho Lim1, and Sang Hyun Ahn†
  • School of Chemical Engineering and Material Science, Chung-Ang University, 84 Heukseok-Ro, Dongjak-Gu, Seoul 06974, Republic of Korea
  • 1Department of Chemical Engineering, Soongsil University, 369 Sangdo-Ro, Dongjak-Gu, Seoul 06978, Republic of Korea
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Porous Sn and Sn-based binary catalysts are facilely fabricated by an electrodeposition method. Varying conditions for Sn electrodeposition enables a control of Sn roughness, which exhibits a significant effect on catalytic performance for electrochemical CO2 reduction. At a specific applied potential, the porous Sn catalyst with relative roughness factor of 56.5 demonstrates a HCOOH Faradaic efficiency of 40.7% with a H2/CO ratio of 2.2. Further improvement of the HCOOH Faradaic efficiency to 59.2% is achieved by using a porous Sn0.29In0.71 catalyst. This catalyst also achieves a H2/CO ratio of 2.2, which can be used as syngas to produce value-added hydrocarbons.
Keywords:Electrochemical CO2 reduction;Foam structure;Electrodeposition;HCOOH;Syngas
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