화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.20, No.3, 1103-1108, May, 2014
Effect of different organosolv treatments on the structure and properties of olive tree pruning lignin
E-mail:
Different organosolv processes (acetosolv, formosolv and acetosolv/formosolv) were applied to extract lignin from olive tree pruning. Obtained lignins were characterized by several methods to determine their composition, structure and functional groups with the aim of evaluating their potential to be used for obtaining added value compounds. All lignins had very high purity and low sugar and inorganic contamination, especially in the case of lignin obtained from formosolv treatment. Hydroxyl groups were the main functional groups in all lignin samples while the carbonyl groups were the lowest. Finally, the main difference between the lignins was the average molecular weight.
  1. Garcia A, Toledano A, Serrano L, Egues I, Gonzalez M, Marin F, Labidi J, Sep. Purif. Technol., 68(2), 193 (2009)
  2. Kleinert M, Barth T, Chem. Eng. Technol., 31(5), 736 (2008)
  3. Gosselink RJA, PhD Thesis. Wageningen University, 2011.
  4. Sahin HT, Appl. Biol. Sci., 1(1), 63 (2003)
  5. Ligero P, Vega A, Bao M, Ind. Crop. Prod., 21, 235 (2005)
  6. Dapia S, Santos V, Parajo JC, Biomass Bioenerg., 22(3), 213 (2002)
  7. Villaverde JJ, Ligero P, Vega A, J. Clean Prod., 18, 395 (2010)
  8. Sahin HT, Young RA, Ind. Crop. Prod., 28, 24 (2008)
  9. Toledano A, Serrano L, Labidi J, Chem. Eng. J., 193-194, 396 (2012)
  10. TAPPI Standards, TAPPI Test Methods, Atlanta, 2007.
  11. Wise LE, Murphy M, D’Adieco AA, Paper Trade J., 122(2), 35 (1946)
  12. Rowell R, The Chemistry of Solid Wood: Based on Short Course and Symposium Sponsored by the Division of Cellulose Paper and Textile Chemistry at the 185th Meeting of the American Chemical Society, Seattle, Washington,(1983), pp. 70.72.
  13. PARAJO JC, ALONSO JL, SANTOS V, Bioresour. Technol., 51(2-3), 153 (1995)
  14. Vila C, Santos V, Parajo JC, Bioresour. Technol., 90(3), 339 (2003)
  15. Xu F, Sun JX, Sun RC, Fowler P, Baird MS, Ind. Crop. Prod., 23, 180 (2006)
  16. Garcia A, Alriols AG, Spigno G, Labidi J, Biochem. Eng. J., 67, 173 (2012)
  17. Mancera C, Ferrando F, Salvado J, El Mansouri NE, Biomass Bioenerg., 35(5), 2072 (2011)
  18. Buranov AU, Ross KA, Mazza G, Bioresour. Technol., 101(19), 7446 (2010)
  19. Toledano A, Erdocia X, Serrano L, Labidi J, Environ. Prog. Sustain. Energ., http://dx.doi.org/10.1002/ep.11725 (2012)
  20. Serrano L, Egues I, Alriols MG, Llano-Ponte R, Labidi J, Chem. Eng. J., 156(1), 49 (2010)
  21. Hage RE, Brosse N, Chrusciel L, Sanchez C, Sannigrahi P, Ragauskas A, Polym. Degrad. Stabil., 94, 1632 (2009)
  22. Alriols MG, Garcia A, Llano-ponte R, Labidi J, Chem. Eng. J., 157(1), 113 (2010)
  23. Sun SN, Li MF, Yuan TQ, Xu F, Sun RC, Ind. Crop. Prod., 37, 51 (2012)
  24. Lora J, in: Belgacem NM, Gandini A (Eds.), Monomer, Polymers and Composites from Renewable Resources, Elsevier Science, 2008, pp. 225.241.
  25. Li JB, Henriksson G, Gellerstedt G, Bioresour. Technol., 98(16), 3061 (2007)
  26. Zhang JH, Deng HB, Lin L, Sun Y, Pan CS, Liu SJ, Bioresour. Technol., 101(7), 2311 (2010)
  27. Rencoret J, Gutierrez A, Nieto L, Barbero JJ, Faulds CB, Kim H, Ralph J, Martinez AT, del Rio JC, Plant Physiol., 55, 667 (2010)
  28. Gottlieb HE, Kotlyar V, Nudelman A, J. Org. Chem., 62, 7512 (1997)
  29. Wei X, Ye L, Yuan Y, J. Nat. Gas Chem., 18(3), 295 (2009)
  30. Robert D, in: Lin SY, Dence CW (Eds.), Methods in Lignin Chemistry, Springer-Verlag, Berlin, 1992, pp. 250.273.
  31. Evtuguin DV, Neto CP, Silva AMS, Domingues PM, Amado FML, Robert D, Faix O, J. Agric. Food Chem., 49, 4252 (2001)