Adsorption and photocatalytic degradation of organic dyes onto crystalline and amorphous hydroxyapatite: Optimization, kinetic and isotherm studies

Solmaz Valizadeh; Mohammad Hossein Rasoulifard; Mir Saeed Seyed Dorraji

Korean Journal of Chemical Engineering, Vol.33, No.2, 481-489, February, 2016

DOI10.1007/s11814-015-0172-1 Export Citation

Adsorption and photocatalytic degradation of organic dyes onto crystalline and amorphous hydroxyapatite: Optimization, kinetic and isotherm studies

Solmaz Valizadeh, Mohammad Hossein Rasoulifard^†, and Mir Saeed Seyed Dorraji

Applied Chemistry Research Laboratory, Department of Chemistry, Faculty of Science, University of Zanjan, Zanjan, Iran

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We evaluated the adsorptive/photodegradation properties of hydroxyapatite. Hydroxyapatite was synthesized by two different precipitation methods and examined for the removal of two kinds of textile dye. The physicochemical properties of the products were characterized using Fourier transform infrared, X-ray diffraction, inductively coupled plasma atomic emission spectroscopy and scanning electron microscopy. The effects of different parameters, including hydroxyapatite synthesis method and removal process type, pH, reaction time, temperature and amount of hydroxyapatite, were investigated and optimized by Taguchi design. The kinetics of adsorption and isotherm studies showed that the pseudo-second-order model and the Freundlich isotherm were the best choices to describe the adsorptive behavior of hydroxyapatite. Photocatalytic degradation of dye followed Langmuir-Hinshelwood mechanism, illustrated a pseudo-first-order kinetic model with the adsorption equilibrium constant and kinetic rate constant of surface reaction equal to 0.011 (l mg.1) and 1.3 (mg l.1 min.1), respectively.

Keywords:Hydroxyapatite;Crystalline;Amorphous;Dye;Adsorption;Photodegradation

[References]

Seo Y, Kim JH, J. Ind. Eng. Chem., 19(2), 488 (2013)
Arunagiri A, Priya K, Kalaichelvi P, Anantharaj R, J. Ind. Eng. Chem., 20(4), 2409 (2014)
Asadullah M, Kabir MS, Ahmed MB, Razak NA, Rasid NSA, Aezzira A, Korean J. Chem. Eng., 30(12), 2228 (2013)
Safavi A, Momeni S, J. Hazard. Mater., 201-202, 125 (2012)
Thongrom B, Amornpitoksuk P, Suwanboon S, Baltrusaitis J, Korean J. Chem. Eng., 31(4), 587 (2014)
Kong L, Zhang Z, Xing H, Yang Q, Su B, Bao Z, Yang Y, Ren Q, Korean J. Chem. Eng., 32(3), 511 (2015)
Korbahti BK, Artut K, Gecgel C, Ozer A, Chem. Eng. J., 173(3), 677 (2011)
Yagub MT, Sen TK, Afroze S, Ang HM, Adv. Colloid Interface Sci., 209, 172 (2014)
Khataee AR, Zarei M, Ordikhani-Seyedlar R, J. Mol. Catal. A-Chem., 338(1-2), 84 (2011)
Chowdhury S, Balasubramanian R, Appl. Catal. B: Environ., 160-161, 307 (2014)
Nezamzadeh-Ejhieh A, Zabihi-Mobarakeh H, J. Ind. Eng. Chem., 20(4), 1421 (2014)
Nasiri-Tabrizi B, Fahami A, Ebrahimi-Kahrizsangi R, J. Ind. Eng. Chem., 20(1), 245 (2014)
Perut F, Montufar EB, Ciapetti G, Santin M, Salvage J, Traykova T, Planell JA, Ginebra MP, Baldini N, Acta Biomater., 7, 1780 (2011)
Svanborg LM, Hoffman M, Andersson M, Currie F, Kjellin P, Wennerberg A, Int. J. Oral Maxillofac. Surg., 40, 308 (2011)
Barka N, Qourzal S, Assabbane A, Nounah A, AIT-Ichou Y, J. Environ. Sci., 20, 1268 (2008)
Chun SY, An SW, Lee SJ, Kim JT, Chang SW, Korean J. Chem. Eng., 31(6), 994 (2014)
Shariffuddin JH, Jones MI, Patterson DA, Chem. Eng. Res. Des., 91(9), 1693 (2013)
Wijesinghe WPSL, Mantilaka MMMGPG, Premalal EVA, Herath HMTU, Mahalingam S, Edirisinghe M, Rajapakse RPVJ, Rajapakse RMG, Mater. Sci. Eng., 42, 83 (2014)
Yang ZP, Gong XY, Zhang CJ, Chem. Eng. J., 165(1), 117 (2010)
Aber S, Salari D, Parsa MR, Chem. Eng. J., 162(1), 127 (2010)
Mohammadi T, Safavi MA, Desalination, 249(1), 83 (2009)
Nishikawa H, Omamiuda K, J. Mol. Catal. A-Chem., 179(1-2), 193 (2002)
Poinern GEJ, Ghosh MK, Ng YJ, Issa TB, Anand S, Singh P, J. Hazard. Mater., 185, 29 (2011)
Stotzel C, Muller FA, Reinert F, Niederdraenk F, Barralet JE, Gbureck U, Colloids Surf. B: Biointerfaces, 74, 91 (2009)
Reddy MP, Venugopal A, Subrahmanyam M, Appl. Catal. B: Environ., 69(3-4), 164 (2007)
Yu X, Tong S, Ge M, Zuo J, Carbohydr. Polym., 92, 269 (2013)
Vucrovic VM, Razmovski RN, Miljic UD, Puskas VS, J. Taiwan Inst. Chem. E., 45, 1700 (2014)
Malkoc E, J. Hazard. Mater., 137(2), 899 (2006)
Mirmohseni A, Dorraji MSS, Figoli A, Tasselli F, Bioresour. Technol., 121, 212 (2012)
Mourabet M, El Rhilassi A, El Boujaady H, Bennani-Ziatni M, El Hamri R, Taitai A, J. Saudi Chem. Soc., 10.1016/j.jscs.2012.03.003. (2012)
Lin KL, Pan JY, Chen YW, Cheng RM, Xu XC, J. Hazard. Mater., 161(1), 231 (2009)
Daneshvar N, Rasoulifard MH, Khataee AR, Hosseinzadeh F, J. Hazard. Mater., 143(1-2), 95 (2007)

[Referenced By]

[1] Seo Y, Kim JH, J. Ind. Eng. Chem., 19(2), 488 (2013)

[2] Arunagiri A, Priya K, Kalaichelvi P, Anantharaj R, J. Ind. Eng. Chem., 20(4), 2409 (2014)

[3] Asadullah M, Kabir MS, Ahmed MB, Razak NA, Rasid NSA, Aezzira A, Korean J. Chem. Eng., 30(12), 2228 (2013)

[4] Safavi A, Momeni S, J. Hazard. Mater., 201-202, 125 (2012)

[5] Thongrom B, Amornpitoksuk P, Suwanboon S, Baltrusaitis J, Korean J. Chem. Eng., 31(4), 587 (2014)

[6] Kong L, Zhang Z, Xing H, Yang Q, Su B, Bao Z, Yang Y, Ren Q, Korean J. Chem. Eng., 32(3), 511 (2015)

[7] Korbahti BK, Artut K, Gecgel C, Ozer A, Chem. Eng. J., 173(3), 677 (2011)

[8] Yagub MT, Sen TK, Afroze S, Ang HM, Adv. Colloid Interface Sci., 209, 172 (2014)

[9] Khataee AR, Zarei M, Ordikhani-Seyedlar R, J. Mol. Catal. A-Chem., 338(1-2), 84 (2011)

[10] Chowdhury S, Balasubramanian R, Appl. Catal. B: Environ., 160-161, 307 (2014)

[11] Nezamzadeh-Ejhieh A, Zabihi-Mobarakeh H, J. Ind. Eng. Chem., 20(4), 1421 (2014)

[12] Nasiri-Tabrizi B, Fahami A, Ebrahimi-Kahrizsangi R, J. Ind. Eng. Chem., 20(1), 245 (2014)

[13] Perut F, Montufar EB, Ciapetti G, Santin M, Salvage J, Traykova T, Planell JA, Ginebra MP, Baldini N, Acta Biomater., 7, 1780 (2011)

[14] Svanborg LM, Hoffman M, Andersson M, Currie F, Kjellin P, Wennerberg A, Int. J. Oral Maxillofac. Surg., 40, 308 (2011)

[15] Barka N, Qourzal S, Assabbane A, Nounah A, AIT-Ichou Y, J. Environ. Sci., 20, 1268 (2008)

[16] Chun SY, An SW, Lee SJ, Kim JT, Chang SW, Korean J. Chem. Eng., 31(6), 994 (2014)

[17] Shariffuddin JH, Jones MI, Patterson DA, Chem. Eng. Res. Des., 91(9), 1693 (2013)

[18] Wijesinghe WPSL, Mantilaka MMMGPG, Premalal EVA, Herath HMTU, Mahalingam S, Edirisinghe M, Rajapakse RPVJ, Rajapakse RMG, Mater. Sci. Eng., 42, 83 (2014)

[19] Yang ZP, Gong XY, Zhang CJ, Chem. Eng. J., 165(1), 117 (2010)

[20] Aber S, Salari D, Parsa MR, Chem. Eng. J., 162(1), 127 (2010)

[21] Mohammadi T, Safavi MA, Desalination, 249(1), 83 (2009)

[22] Nishikawa H, Omamiuda K, J. Mol. Catal. A-Chem., 179(1-2), 193 (2002)

[23] Poinern GEJ, Ghosh MK, Ng YJ, Issa TB, Anand S, Singh P, J. Hazard. Mater., 185, 29 (2011)

[24] Stotzel C, Muller FA, Reinert F, Niederdraenk F, Barralet JE, Gbureck U, Colloids Surf. B: Biointerfaces, 74, 91 (2009)

[25] Reddy MP, Venugopal A, Subrahmanyam M, Appl. Catal. B: Environ., 69(3-4), 164 (2007)

[26] Yu X, Tong S, Ge M, Zuo J, Carbohydr. Polym., 92, 269 (2013)

[27] Vucrovic VM, Razmovski RN, Miljic UD, Puskas VS, J. Taiwan Inst. Chem. E., 45, 1700 (2014)

[28] Malkoc E, J. Hazard. Mater., 137(2), 899 (2006)

[29] Mirmohseni A, Dorraji MSS, Figoli A, Tasselli F, Bioresour. Technol., 121, 212 (2012)

[30] Mourabet M, El Rhilassi A, El Boujaady H, Bennani-Ziatni M, El Hamri R, Taitai A, J. Saudi Chem. Soc., 10.1016/j.jscs.2012.03.003. (2012)

[31] Lin KL, Pan JY, Chen YW, Cheng RM, Xu XC, J. Hazard. Mater., 161(1), 231 (2009)

[32] Daneshvar N, Rasoulifard MH, Khataee AR, Hosseinzadeh F, J. Hazard. Mater., 143(1-2), 95 (2007)