화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.65, 180-187, September, 2018
DOI10.1016/j.jiec.2018.04.027  Export Citation
Electrochemical characterization and thermodynamic tendency of β-Lactoglobulin adsorption on 3D printed stainless steel
M.J.K Lodhi1, K.M. Deen2, 3, Zia Ur Rahman1, 4, Ameeq Farooq3, and Waseem Haider1, 4, †
  • 1School of Engineering and Technology, Central Michigan University, Mt. Pleasant, MI, USA
  • 2Department of Materials Engineering, University of British Columbia, Vancouver, BC V6T 1Z4, Canada
  • 3Corrosion Control Research Cell, Department of Metallurgy and Materials Engineering, University of the Punjab, Lahore 54590, Pakistan
  • 4Science of Advanced Materials, Central Michigan University, Mt. Pleasant, MI, USA
E-mail:
The electrochemical behavior of 3D printed 316L stainless steel (3DPSS) was investigated in phosphate buffer saline (PBS), containing β-Lactoglobulin (BLG). The charge transfer resistance (Rct) was decreased from 629 to 40Ω V cm2 with an increase in temperature from 293 to 323 K in BLG free electrolyte. At each temperature, the exponential decrease in the polarization resistance (Rp) of 3DPSS was a function of BLG concentration. The significant decrease in activation energy ‘Ea’ (~15 kJ mol-1) upon adding 0.06 g/L BLG attributed to the charge transfer process involved in the adsorption process. The results were further used to quantify the thermodynamic parameters.
Keywords:3D printed 316L stainless steel;β-Lactoglobulin;Electrochemical;Polarization resistance;Thermodynamic parameters
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