화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.70, 264-275, February, 2019
DOI10.1016/j.jiec.2018.10.025  Export Citation
Novel WO3/Fe3O4 magnetic photocatalysts: Preparation, characterization and thiacloprid photodegradation
Nemanja D. Banic, Biljana F. Abramovic†, Jugoslav B. Krstic1, Daniela V. Sojic Merkulov, Nina L. Fincur, and Miodrag N. Mitric2
  • Faculty of Sciences, Department of Chemistry, Biochemistry and Enivronmental Protection, University of Novi Sad, Trg D. Obradovica 3, 21000 Novi Sad, Serbia
  • 1Institute OF Chemisry, Technology and Metallurgy, Department of Catalysis an Chemical Engineering, University of Belgrade, Njegoseva 12, 11000 Belgrade, Serbia
  • 2Vinca Institute of Nuclear Sciences, University of Belgrade, Mike Petrovica Alasa 12-14, 11001 Belgrade, Sebia, Serbia
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This work presents the characterization of novel synthesized WO3/Fe3O4 catalysts and investigates their photocatalytic activity for thiacloprid decomposition under UV and simulated sunlight radiation. Four WO3/Fe3O4 nanopowders with different amounts of WO3 were synthesized by chemical co-precipitation method. XRD analysis showed the presence of hematite and magnetite nano-dimensional phases of Fe3O4 in the catalysts. The magnetite phase content increased with increasing WO3 content. Degradation efficiency of thiacloprid in the presence of 6.1WO3/Fe3O4/H2O2 under simulated solar radiation was 2.2 times higher compared to Fe3O4. Under an external magnetic field, a significant increase in the catalysts separation from reaction mixture was observed.
Keywords:WO3/Fe3O4;Photodegradation;Thiacloprid;Hematite/magnetite;Magnetic separation
  1. Ping WX, Chao SD, Dong YT, Sci. China, 59, 1899 (2016)
  2. Brillas E, Martinez-Huitle CA, Appl. Catal. B: Environ., 166-167, 603 (2015)
  3. Naidu R, Espana VAA, Liu Y, Jit J, Chemosphere, 154, 350 (2016)
  4. World Health Organization, Drinking-Water, Fact Sheet, (2017) http://www.who.int/mediacentre/factsheets/fs391/en/. (Accessed 22 January 2018).
  5. Shahidi D, Roy R, Azzouz A, Appl. Catal. B: Environ., 174-175, 277 (2015)
  6. Xiao J, Xie Y, Cao H, Chemosphere, 121, 1 (2015)
  7. Chong MN, Jin B, Chow CWK, Saint C, Water Res., 44, 2997 (2010)
  8. Zhang ZY, Kong JL, J. Hazard. Mater., 193, 325 (2011)
  9. Zhang S, Niu H, Hu Z, Cai Y, Shi Y, J. Chromatogr. A, 1217, 4757 (2010)
  10. Tang JW, Zou ZG, Ye JH, Catal. Lett., 92(1-2), 53 (2004)
  11. Kumar SG, Rao KSRK, RSC Adv., 5, 3306 (2015)
  12. Rahimi-Nasrabadi M, Behpour M, Sobhani-Nasab A, Jeddy MR, J. Mater. Sci. Mater. Electron., 27, 11691 (2016)
  13. Ahmadi F, Rahimi-Nasrabadi M, Fosooni A, Daneshmand M, J. Mater. Sci. Mater. Electron., 27, 9514 (2016)
  14. Lee KM, Lai CW, Ngai KS, Juan JC, Water Res., 88, 428 (2016)
  15. Rahimi-Nasrabadi M, Ahmadi F, Fosooni A, J. Mater. Sci. Mater. Electron., 28, 537 (2017)
  16. Zapata A, Oller I, Bizani E, Sanchez-Perez JA, Maldonado MI, Malato S, Catal. Today, 144, 94 (2009)
  17. Pignatello JJ, Environ. Sci. Technol., 26, 944 (1992)
  18. Malato S, Blanco J, Vidal A, Richter C, Appl. Catal. B: Environ., 37(1), 1 (2002)
  19. Coupe RH, Blomquist JD, J. Am. Water Works Assoc., 96, 56 (2004)
  20. Jeschke P, Nauen R, Schindler M, Elbert A, J. Agric. Food Chem., 59, 2897 (2011)
  21. Guzsvany V, Csanadi J, Gaal F, Acta Chim. Slov., 53, 52 (2006)
  22. Cernigoj U, Stangar UL, Trebse P, Appl. Catal. B: Environ., 75(3-4), 229 (2007)
  23. Dell’Arciprete ML, Santos-Juanes L, ArquesSanz A, Vicente R, Amat AM, Furlong JP, Martire DO, Gonzales MC, Photochem. Photobiol. Sci., 8, 1016 (2009)
  24. Cernigoj U, Stangar UL, Jirkovsky J, J. Hazard. Mater., 177(1-3), 399 (2010)
  25. Abramovic BF, Banic ND, Sojic DV, Chemosphere, 81, 114 (2010)
  26. Banic N, Abramovic B, Krstic J, Sojic D, Loncarevic D, Cherkezova-Zheleva Z, Guzsvany V, Appl. Catal. B: Environ., 107(3-4), 363 (2011)
  27. Abramovic BF, Banic ND, Krstic JB, Ind. Eng. Chem. Res., 52(14), 5040 (2013)
  28. Banic ND, Abramovic BF, Sojic DV, Krstic JB, Fincur NL, Bakovic IP, Chem. Eng. J., 286, 184 (2016)
  29. Banic ND, Sojic DV, Krstic JB, Abramovic BF, Water Air Soil Pollut., 225, 1954 (2014)
  30. Cornell RM, Schwertmann U, The Iron Oxides: Structure, Properties, Reactions, Occurrences and Uses, Wiley VCH, Weinheim, 2003.
  31. Gotic M, Ivanda M, Popovic S, Music S, Mater. Sci. Eng., 77, 193 (2000)
  32. Zheng HD, Ou JZ, Strano MS, Kaner RB, Mitchell A, Kalantar-Zadeh K, Adv. Funct. Mater., 21(12), 2175 (2011)
  33. Huirache-Acuna R, Paraguay-Delgado F, Albiter MA, Lara-Romero J, Martinez-Sanchez R, Mater. Charact., 60, 932 (2009)
  34. Sanchez-Martinez D, Martinez-de la Cruz A, Lopez-Cuellar E, Mater. Res. Bull., 48(2), 691 (2013)
  35. Cheary RW, Coelho AA, J. Appl. Crystallogr., 25, 109 (1992)
  36. Thommes M, Kaneko K, Neimark AV, Olivier JP, Rodriguez-Reinoso F, Rouquerol J, Sing KS, Pure Appl. Chem., 87, 1051 (2015)
  37. Dubinin MM, Progress in Surface and Membrane Science, vol. 9, AcademicPress, NY, 1975.
  38. Barrett EP, Joyner LG, Halenda PP, J. Am. Chem. Soc., 73, 373 (1951)
  39. Lecloux A, Pirard JP, J. Colloid Interface Sci., 70, 265 (1979)
  40. Banic N, Vranes M, Abramovic B, Csana'di J, Gadzuric S, Dalton Trans., 43, 15515 (2014)
  41. Sun W, Yeung MT, Lech AT, Lin CW, Lee C, Li T, Duan X, Zhou J, Kaner RB, Nano Lett., 15, 4834 (2015)
  42. Marques AC, Santos L, Costa MN, Dantas JM, Duarte P, Goncalves A, Martins R, Salgueiro CA, Fortunato E, Sci. Rep. UK, 5, 9910 (2015)
  43. Cao X, Prozorov R, Koltypin Y, Kataby G, Felner I, Gedanke A, J. Mater. Res., 12, 402 (1997)
  44. Lehlooh AF, Mahmood S, Abu-Aljarayesh I, J. Magn. Magn. Mater., 136, 143 (1994)
  45. Monazam ER, Breault RW, Siriwardane R, Ind. Eng. Chem. Res., 53(34), 13320 (2014)
  46. Cullity BD, Introduction to Magnetism and Magnetic Materials, Addison-Wesley, MA, 1972.
  47. Guardia P, Labarta A, Batlle X, J. Phys. Chem. C, 115, 390 (2010)
  48. Thapa D, Palkar VR, Kurup MB, Malik SK, Mater. Lett., 58, 2692 (2004)
  49. Andrzejewski B, Bednarski W, Kazmierczak M, Lapinski A, et al., Compos. B Eng., 64, 147 (2014)
  50. Caruntu D, Caruntu G, O’Connor CJ, J. Phys. D-Appl. Phys., 40, 5801 (2007)
  51. Zhuang L, Zhang W, Zhao Y, Shen H, Lin H, Liang J, Sci. Rep. UK, 5, 9320 (2015)
  52. Singh AK, Srivastava ON, Singh K, Nanoscale Res. Lett., 12, 298 (2017)
  53. Malato S, Fernandez-Ibanez P, Maldonado MI, Blanco J, Gernjak W, Catal. Today, 147(1), 1 (2009)
  54. Qamar M, Muneer M, Desalination, 249(2), 535 (2009)
  55. Ejhieha AN, Khorsandi M, J. Hazard. Mater., 176(1-3), 629 (2010)
  56. Liang CH, Hou MF, Zhou SG, Li FB, Liu CS, Liu TX, Gao YX, Wang XG, Lu HL, J. Hazard. Mater., 138(3), 471 (2006)
  57. Lin SS, Gurol MD, Environ. Sci. Technol., 32, 1417 (1998)
  58. Banic N, Abramovic B,Sibul F, Orcic D, Watson M, Vranes M, Gadzuric S, RSC Adv., 6, 52826 (2016)
  59. Serpone N, Maruthamuthu P, Pichat P, Pelizzetti E, Hidaka H, J. Photochem. Photobiol. A-Chem., 85, 247 (1995)
  60. Bessekhouad Y, Robert D, Weber JV, J. Photochem. Photobiol. A-Chem., 163, 569 (2004)
  61. Stefan MI, Hoy AR, Bolton JR, Environ. Sci. Technol., 30, 2382 (1996)
  62. Tryba B, Morawski AW, Inagaki M, Toyoda M, Appl. Catal. B: Environ., 63(3-4), 215 (2006)
  63. Huang H, Han X, Li X, Wang S, Chu PK, Zhang Y, ACS Appl. Mater. Interfaces, 7, 482 (2015)
  64. Huang HW, Xiao K, He Y, Zhang TR, Dong F, Du X, Zhang YH, Appl. Catal. B: Environ., 199, 75 (2016)
  65. Huang HW, Xiao K, Zhang TR, Dong F, Zhang YH, Appl. Catal. B: Environ., 203, 879 (2017)
  66. Wu W, Jiang C, Roy VAL, Nanoscale, 7, 38 (2015)
  67. Huang H, Li X, Wang J, Dong F, Chu PK, Zhang T, Zhang Y, ACS Catal., 5, 4094 (2015)
  68. Huang H, Tu S, Zeng C, Zhang T, Reshak AH, Zhang Y, Angew. Chem.-Int. Edit., 56, 11860 (2017)
  69. Dantas TLP, Humberto JJ, Moreira RFPM, Acta Sci. Technol., 25, 91 (2003)
  70. Byrne JM, Van der Laan G, Figueroa JI, Qafoku O, Wang C, Pearce CI, Jackson M, Feinberg J, Rosso KM, Kappler A, Sci. Rep., 6, 30969 (2016)