화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.76, 1-16, August, 2019
DOI10.1016/j.jiec.2019.03.022  Export Citation
A review on the Mo-precursors for catalytic hydroconversion of heavy oil
Ki Hyuk Kang, Gyoo Tae Kim, Sunyoung Park, Pill Won Seo, Hwimin Seo, and Chul Wee Lee†
  • Center for Convergent Chemical Process, Korea Research Institute of Chemical Technology (KRICT), Daejeon, 34114, Republic of Korea
E-mail:
MoS2 is known as core material for the hydroconversion of heavy oil in petroleum refinery due to its superior coke suppression and desulfurization activities. With the recent interest in applying MoS2 to slurry-bed reactors, it has become important to design appropriate Mo-precursors and to identify factors for evaluating them. In this review, various methods for the synthesis of MoS2 from Mo-precursors and their physicochemical properties were examined. It was revealed that several properties of Mo-precursors (dispersibility and thermal properties) and MoS2 (sulfidation degree, particle size, and stacking) serve as crucial factors in determining catalytic performance. For better catalyst design, the decomposition pathway of Mo-precursors and the effect of carbonaceous material on MoS2 were also discussed.
Keywords:Hydroconversion;Heavy oil;VR;Mo-precursor;MoS2;Dispersed catalyst
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