화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.76, 429-436, August, 2019
A fundamental approach to design of injectable high-content gel polymer electrolyte for activated carbon electrode supercapacitors
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An injectable high-content gel polymer electrolyte (GPE) was designed so that highly-entangled polymer matrix was situated in bulk electrolyte of supercapacitors (SCs) and SBP+/BF4 - ions were more concentrated in pores of activated carbon (AC) particles, thereby facilitating ion transport. Compared with the SCs containing the liquid electrolyte (1 M SBPBF4/AN), the SCs containing the injectable GPE showed 5% higher capacitance (12% reduced Warburg resistance) at 20 ℃ and 52% higher capacitance (95% retention) after 16-h storage at 80 ℃(boiling point of AN). This study provides insight into the developments of novel GPE processes for high-energy AC electrode SCs.
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