화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.77, 76-82, September, 2019
DOI10.1016/j.jiec.2019.04.021  Export Citation
New synthesis strategy for hollow NiO nanofibers with interstitial nanovoids prepared via electrospinning using camphene for anodes of lithium-ion batteries
Jang Hyeok Oh, Min Su Jo, Sang Mun Jeong1, Chungyeon Cho2, Yun Chan Kang3, †, and Jung Sang Cho†
  • Department of Engineering Chemistry, Chungbuk National University, Gaesin-Dong, Seowon-Gu, Cheongju, 361-763, Republic of Korea
  • 1Department of Chemical Engineering, Chungbuk National University, Gaesin-Dong, Seowon-Gu, Cheongju, 361-763, Republic of Korea
  • 2Department of Carbon Convergence Engineering, College of Engineering, Wonkwang University, Iksan, Jeonbuk, 54538, South Korea
  • 3Department of Materials Science and Engineering, Korea University, Anam-Dong, Seongbuk-Gu, Seoul, 136-713, Republic of Korea
E-mail:,
This paper introduces a new synthesis strategy suitable for the one-step synthesis of hollow 1- dimensition nanostructures and highly desirable for the simple preparation of well-defined hollow nanostructures with high product yields using camphene. The viscosity gradient of the jet during the electrospinning results in the inward movement of the camphene. Subsequently, the sublimation of camphene generates internal hollow space without further processing. The resulting nanofibers exhibit a reversible discharge capacity of 956 mA h g-1 after 400 cycles when applied as anodes for lithium-ion batteries. The discharge capacities of the nanofibers are 1050, 1024, 937, 796, 643, and 483 mA h g-1 at current densities of 0.5, 1.5, 3.0, 5.0, 7.0, and 10.0 A g-1, respectively. The NiO nanofibers with hollow structure show high structural stability and shorten the Li+-ion diffusion pathway during cycles, which resulted in excellent lithium-ion storage properties.
Keywords:Hollow structure;Electrospinning;NiO;Camphene;Anodes
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