화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.77, 449-460, September, 2019
DOI10.1016/j.jiec.2019.05.011  Export Citation
Experimental and theoretical studies on inhibition performance of Cu corrosion in 0.5 M H2SO4 by three disulfide derivatives
Bochuan Tan, Shengtao Zhang†, Wenpo Li†, Xiuli Zuo1, Yujie Qiang, Lihui Xu2, Jiangyu Hao, and Shijin Chen3
  • School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, China
  • 1Department of Petroleum, Army Logistics University of PLA, Chongqing 401331, China
  • 2School of the Civil Engineering, Beijing Jiaotong University, Beijing 100044,China
  • 3Bomin Electronics Ltd., Meizhou 514021, China
E-mail:,
Phenyl disulfide (PDF), 2,2'-dithiodipyridine (DDP), 5,5-dithiobis(1-phenyl-1H-tetrazole) (DPT) were studied as inhibitors for Cu in H2SO4 via electrochemical methods, surface morphology analysis and theoretical calculations. Electrochemical experiments show that PDF, DDP and DPT can exhibit excellent corrosion inhibition performance. Their order of corrosion inhibition is DPT > DDP > PDF. Surface morphology analysis supports the electrochemical results. The X-ray photoelectron spectroscopy (XPS) results show that S-Cu bonds are detected in PDF, DDP and DPT, and N-Cu bonds are detected in DDP and DPT. PDF, DDP and DPT adsorption on the Cu surface obey the Langmuir isotherm model. The results of quantum chemical calculations show that DPT has more active reaction sites than DDP and PDF. Molecular dynamics simulation results show that the order of binding energies of the three corrosion inhibitor molecules on the copper surface is DPT > DDP > PDF.
Keywords:Cu;Corrosion inhibitor;Electrochemical experiment;XPS;Molecular dynamics simulation
  1. Mo S, Luo HQ, Li NB, J. Colloid Interface Sci., 505, 929 (2017)
  2. Tan BC, Zhang ST, Qiang YJ, Guo L, Feng L, Liao CH, Xu Y, Chen SJ, J. Colloid Interface Sci., 526, 268 (2018)
  3. Solmaz R, Sahin EA, Doner A, Kardas G, Corrosion Sci., 53, 3231 (2011)
  4. Bozorg M, Farahani TS, Neshati J, Chaghazardi Z, Ziarani GM, Ind. Eng. Chem. Res., 53(11), 4295 (2014)
  5. Amin MA, Khaled KF, Corrosion Sci., 52, 1194 (2010)
  6. Kannan P, Rao TS, Rajendran N, J. Colloid Interface Sci., 512, 618 (2018)
  7. Quartarone G, Battilana M, Bonaldo L, Tortato T, Corrosion Sci., 50, 3467 (2008)
  8. Tan B, Zhang S, Qiang Y, Feng L, Liao C, Xu Y, Chen S, J. Mol. Liq., 248, 902 (2017)
  9. Rassouli L, Naderi R, Mahdavain M, J. Ind. Eng. Chem., 66, 221 (2018)
  10. Solomon MM, Umoren SA, J. Colloid Interface Sci., 462, 29 (2016)
  11. Qiang Y, Fu S, Zhang S, Chen S, Zou X, Corrosion Sci., 140, 111 (2018)
  12. Ramezanzadeh M, Sanaei Z, Bahlakeh G, Ramezanzadeh B, J. Mol. Liq., 256, 67 (2018)
  13. Sanaei Z, Ramezanzadeh M, Bahlakeh G, Ramezanzadeh B, J. Ind. Eng. Chem., 69, 18 (2019)
  14. Han P, Chen C, Li W, Yu H, Xu Y, Ma L, Zheng Y, J. Colloid Interface Sci., 516, 398 (2018)
  15. Guo L, Obot IB, Zheng XW, Shen X, Qiang YJ, Kaya S, Kaya C, Appl. Surf. Sci., 406, 301 (2017)
  16. Ehsani A, Mahjani MG, Hosseini M, Safari R, Moshrefi R, Shiri HM, J. Colloid Interface Sci., 490, 444 (2017)
  17. Motamedi M, Ramezanzadeh B, Mahdavian M, J. Ind. Eng. Chem., 66, 116 (2018)
  18. Dohare P, Ansari KR, Quraishi MA, Obot IB, J. Ind. Eng. Chem., 52, 197 (2017)
  19. Guo Y, Xu B, Liu Y, Yang W, Yin X, Chen Y, Le J, Chen Z, J. Ind. Eng. Chem., 56, 234 (2017)
  20. Tasic ZZ, Antonijevic MM, Mihajlovic MBP, Radovanovic MB, J. Mol. Liq., 219, 463 (2016)
  21. Szocs E, Vastag G, Shaban A, Kalman E, Corrosion Sci., 47, 893 (2005)
  22. Khan G, Basirun WJ, Kazi SN, Ahmed P, Magaji L, Ahmed SM, Khan GM, Rehman MA, J. Colloid Interface Sci., 502, 134 (2017)
  23. Khaled KF, Appl. Surf. Sci., 255(5), 1811 (2008)
  24. Tang YM, Yang WZ, Yin XS, Liu Y, Wan R, Wang JT, Mater. Chem. Phys., 116(2-3), 479 (2009)
  25. Liu Y, Xue JZ, Luo D, Wang HY, Gong X, Han ZW, Ren LQ, J. Colloid Interface Sci., 491, 313 (2017)
  26. Wang Z, Gong Y, Jing C, Huang H, Li H, Zhang S, Gao F, Corrosion Sci., 113, 64 (2016)
  27. Qiang Y, Zhang S, Guo L, Zheng X, Xiang B, Chen S, Corrosion Sci., 119, 68 (2017)
  28. Mo S, Li LJ, Luo HQ, Li NB, J. Mol. Liq., 242, 822 (2017)
  29. Jing C, Wang Z, Gong Y, Huang H, Ma Y, Xie H, Li H, Zhang S, Gao F, Corrosion Sci., 138, 353 (2018)
  30. Fouda AEAS, Etaiw SEDH, El-bendary MM, Maher MM, J. Mol. Liq., 213, 228 (2016)
  31. Sudheer, Quraishi MA, Corrosion Sci., 70, 161 (2013)
  32. Tian H, Li W, Hou B, Wang D, Corrosion Sci., 117, 43 (2017)
  33. Mishra A, Verma C, Lgaz H, Srivastava V, Quraishi MA, Ebenso EE, J. Mol. Liq., 251, 317 (2018)
  34. Alvareza MVFBP, Neske A, Brandand SA, Gervasi CA, J. Ind. Eng. Chem., 58, 92 (2018)
  35. Zheng X, Zhang S, Li W, Gong M, Yin L, Corrosion Sci., 95, 168 (2015)
  36. Qiang Y, Zhang S, Yan S, Zou X, Chen S, Corrosion Sci., 126, 295 (2017)
  37. Zhang J, Zhang L, Tao G, J. Mol. Liq., 272, 369 (2018)
  38. Li ML, Xu J, Li RH, Wang DG, Li TB, Yuan MS, Wang JY, J. Colloid Interface Sci., 417, 131 (2014)
  39. Charitha BP, Rao P, J. Ind. Eng. Chem., 58, 357 (2018)
  40. Prabakaran M, Kim SH, Oh YT, Raj V, Chung IM, J. Ind. Eng. Chem., 45, 380 (2017)
  41. Liao LL, Mo S, Lei JL, Luo HQ, Li NB, J. Colloid Interface Sci., 474, 68 (2016)
  42. Gong Z, Peng S, Huang X, Gao L, Materials, 11 (2018)
  43. Prabakaran M, Kim SH, Mugila N, Hemapriya V, Parameswari K, Chitra S, Chung IM, J. Ind. Eng. Chem., 52, 235 (2017)
  44. Haque J, Ansari KR, Srivastava V, Quraishi MA, Obot IB, J. Ind. Eng. Chem., 49, 176 (2017)
  45. Mihajlovic MBP, Radovanovic MB, Tasic ZZ, Antonijevic MM, J. Mol. Liq., 225, 127 (2017)
  46. Lgaz H, Bhat KS, Salghi R, Shubhalaxmi, Jodeh S, Algarra M, Hammouti B, Ali IH, Essamri A, J. Mol. Liq., 238, 71 (2017)
  47. Xu Y, Zhang ST, Li WP, Guo L, Xu SY, Feng L, Madkour LH, Appl. Surf. Sci., 459, 612 (2018)
  48. Wang Y, Liu Z, Li D, Dong Y, Li W, Li N, Corrosion Sci., 98, 382 (2015)
  49. Wang YB, Liu Z, Huang YD, Qi YT, Appl. Surf. Sci., 356, 191 (2015)
  50. Abd El-Raouf M, Khamis EA, Abou Kana MTH, Negm NA, J. Mol. Liq., 255, 341 (2018)
  51. Guo L, Kaya S, Obot IB, Zheng XW, Qiang YJ, J. Colloid Interface Sci., 506, 478 (2017)
  52. Wang H, Hao Y, Chen S, Cheng M, Li C, Sun S, Hu S, Corrosion Sci., 137, 33 (2018)
  53. Liao LL, Mo S, Luo HQ, Li NB, J. Colloid Interface Sci., 520, 41 (2018)
  54. Tan BC, Zhang ST, Liu HY, Guo YW, Qiang YJ, Li WP, Guo L, Xu CL, Chen SJ, J. Colloid Interface Sci., 538, 519 (2019)