Graphene quantum dot-embedded perovskite photodetectors with fast response and enhanced sensitivity through bulk defect passivation

David Sunghwan Lee; Jeong-Seob Yun; Jin Hyuck Heo; Bong Woo Kim; Sang Hyuk Im

Journal of Industrial and Engineering Chemistry, Vol.100, 383-389, August, 2021

DOI10.1016/j.jiec.2021.05.001 Export Citation

Graphene quantum dot-embedded perovskite photodetectors with fast response and enhanced sensitivity through bulk defect passivation

David Sunghwan Lee, Jeong-Seob Yun, Jin Hyuck Heo, Bong Woo Kim, and Sang Hyuk Im^†

Department of Chemical and Biological Engineering, Korea University, 145 Anam-ro, Seongbuk-gu, Seoul 136-713, Republic of Korea

E-mail:

Graphene quantum dots (GQDs) synthesized by single phase solution chemistry are embedded in metal halide perovskite (MHP) films because they can act as passivating defects that are present throughout the MHP film, not only at the interface but also throughout the bulk of the film. The perovskite photodetectors composed of indium-doped tin oxide/SnO2/MHP with embedded GQDs/poly triaryl- amine/Au have the reduced dark current, increased detectivity, and fasted response speed due to lower trap density throughout the bulk MHP layer.

Keywords:Graphene quantum dots;Perovskites;Photodetectors;Fast response;Sensitivity;Bulk defect passivation

[References]

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[2] Li C, Lu J, Zhao Y, Sun L, Wang G, Ma Y, Zhang S, Zhou J, Shen L, Huang W, Small, 15, 190359 (2019)

[3] Subramanian A, Akram J, Hussain S, Chen J, Qasim K, Zhang W, Lei W, ACS Appl. Electron. Mater., 2, 230 (2020)

[4] Park JK, Heo JH, Kim BW, Im SH, J. Ind. Eng. Chem., 92, 167 (2020)

[5] Lee MM, Teuscher J, Miyasaka T, Murakami TN, Snaith HJ, Science, 338(6107), 643 (2012)

[6] Zhao Y, Zhu K, Chem. Soc. Rev., 45, 655 (2016)

[7] Miyata A, Mitioglu A, Plochocka P, Portugall O, Wang JTW, Stranks SD, Snaith HJ, Nicholas RJ, Nat. Phys., 11, 582 (2015)

[8] Fu Y, Zhu H, Chen J, Hautzinger MP, Zhu XY, Jin S, Nat. Rev. Mater., 4, 169 (2019)

[9] Kim BW, Heo JH, Park JK, Lee DSH, Park HI, Kim SY, Kim JH, Im SH, J. Ind. Eng. Chem., 97, 417 (2021)

[10] Heo JH, Im KM, Lee HJ, Kim JS, Im SH, J. Ind. Eng. Chem., 94, 376 (2021)

[11] Walsh A, Scanlon DO, Chen S, Gong XG, Wei SH, Angew. Chem.-Int. Edit., 54, 1791 (2015)

[12] Steirer KX, Schulz P, Teeter G, Stevanovic V, Yang M, Zhu K, Berry JJ, ACS Energy Lett., 1, 360 (2016)

[13] Jahandar M, Khan N, Jahankhan M, Song CE, Lee HK, Lee SK, Shin WS, Lee JC, Im SH, Moon SJ, J. Ind. Eng. Chem., 80, 265 (2019)

[14] Han TH, Tan S, Xue J, Meng L, Lee JW, Yang Y, Adv. Mater., 31, 180351 (2019)

[15] Shan Q, Wei C, Jiang Y, Song J, Zou Y, Xu L, Fang T, Wang T, Dong Y, Liu J, Han B, Zhang F, Chen J, Wang Y, Zeng H, Light Sci. Appl., 9, 163 (2020)

[16] Lee W, Lee J, Yun H, Kim J, Park J, Choi C, Kim DC, Seo H, Lee H, Yu JW, Lee WB, Kim DH, Adv. Mater., 29, 170290 (2017)

[17] Xue J, Zhu Z, Xu X, Gu Y, Wang S, Xu L, Zou Y, Song J, Zeng H, Chen Q, Nano Lett., 28, 7628 (2018)

[18] Wang H, Kim DH, Chem. Soc. Rev., 46, 5204 (2017)

[19] Ahmadi M, Wu T, Hu B, Adv. Mater., 29, 160524 (2017)

[20] Kim Y, Park B, Nanoscale, 10, 20377 (2018)

[21] Shen L, Fang YJ, Wang D, Bai Y, Deng YH, Wang MM, Lu YF, Huang JS, Adv. Mater., 28(48), 10794 (2016)

[22] Shao Y, Xiao Z, Bi C, Yuan Y, Huang J, Nat. Commun., 5, 5784 (2014)

[23] Zheng X, Chen B, Dai J, Fang Y, Bai Y, Lin Y, Wei H, Zeng XC, Huang J, Nat. Energy, 2, 17102 (2017)

[24] Tian P, Tang L, Teng KS, Lau SP, Mater. Today Chem., 10, 221 (2018)

[25] Tajik S, Dourandish Z, Zhang K, Beitollahi H, Le QV, Jang HW, Shokouhimehr M, RSC Adv., 10, 15406 (2020)

[26] Lee SH, Kim DY, Lee J, Lee SB, Han H, Kim YY, Mun SC, Im SH, Kim TH, Park OO, Nano Lett., 19, 5437 (2019)

[27] Chen H, Luo Q, Liu T, Tai M, Lin J, Murugadoss V, Lin H, Wang J, Guo Z, Wang N, ACS Appl. Mater. Interfaces, 12, 13941 (2020)

[28] Fang X, Ding J, Yuan N, Sun P, Lv M, Ding G, Zhu C, Phys. Chem. Chem. Phys., 19, 6057 (2017)

[29] Kim S, Shin DH, Kim CO, Kang SS, Joo SS, Choi SH, Hwang SW, Sone C, Appl. Phys. Lett., 102, 053108 (2013)

[30] Dervishi E, Ji Z, Htoon H, Sykora M, Doorn SK, Nanoscale, 11, 16571 (2019)

[31] Sun Y, Wang S, Li C, Luo P, Tao L, Wei Y, Shi G, Phys. Chem. Chem. Phys., 15, 9907 (2013)

[32] Li LL, Ji J, Fei R, Wang CZ, Lu Q, Zhang JR, Jiang LP, Zhu JJ, Adv. Funct. Mater., 22(14), 2971 (2012)

[33] Jeon NJ, Noh JH, Kim YC, Yang WS, Ryu S, Il Seol S, Nat. Mater., 13(9), 897 (2014)

[34] Kim S, Bae S, Lee SW, Cho K, Lee KD, Kim H, Park S, Kwon G, Ahn SW, Lee HM, Kang Y, Lee HS, Kim D, Sci. Rep., 7, 1200 (2017)

[35] Oku T, Crystal Structures of CH3NH3PbI3 and Related Perovskite Compounds used for Solar Cells-New Approaches and Reviews, IntechOpen, 2015.

[36] Jacobsson TJ, Correa-Baena JP, Anaraki EH, Philippe B, Stranks SD, Bouduban MEF, Tress W, Schenk K, Teuscher J, Moser JE, Rensmo H, Hagfeldt A, J. Am. Chem. Soc., 138(32), 10331 (2016)

[37] Cullity BD, Elements of X-Ray Diffraction, second ed., Pearson, 1978.

[38] Holzwarth U, Gibson N, Nat. Nanotechnol., 6(9), 534 (2011)

[39] deQuilettes DW, Vorpahl SM, Stranks SD, Nagaoka H, Eperon GE, Ziffer ME, Snaith HJ, Ginger DS, Science, 348(6235), 683 (2015)

[40] Shi D, Adinolfi V, Comin R, Yuan MJ, Alarousu E, Buin A, Chen Y, Hoogland S, Rothenberger A, Katsiev K, Losovyj Y, Zhang X, Dowben PA, Mohammed OF, Sargent EH, Bakr OM, Science, 347(6221), 519 (2015)

[41] Fu L, Li H, Wang L, Yin R, Li B, Yin L, Energy Environ. Sci., 13, 4017 (2020)

[42] National Center for Biotechnology Information, PubChem Compound Summary for CID 8926, Hexadecylamine, (2020).

[43] Zhang J, Tong T, Zhang L, Li X, Zhou H, Yu J, ACS Sustain. Chem. Eng., 6, 8631 (2018)

[44] Chen Z, Cheng Z, Wang J, Wan X, Shu C, Tsang HK, Ho HP, Xu JB, Adv. Opt. Mater., 3, 1207 (2015)

[45] Patt BE, Iwanczyk JS, Tull CR, Segal JD, MacDonald LR, Tornai MP, Kenney CJ, Hoffman EJ, IEEE Trans. Nucl. Sci., 47, 957 (2000)

[46] Yuan J, Zhang L, Bi C, Wang M, Tian J, Sol. RRL, 2, 180018 (2018)

[47] Poglitsch A, Weber D, J. Chem. Phys., 87, 6373 (1987)

[48] Yoo SM, Yoon SJ, Ahta JA, Lee HJ, Boix PP, Mora-Sero I, Joule, 3, 2535 (2019)

[49] Bou A, Pockett A, Raptis D, Watson T, Carnie MJ, Bisquert J, J. Phys. Chem. Lett., 11, 8654 (2020)