화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.103, 102-117, November, 2021
DOI10.1016/j.jiec.2021.07.024  Export Citation
S, P-codoped rGO-phytic acid-polythiophene core.shell; synthesis, modeling, and dual active.passive anti-corrosion performance of epoxy nanocomposite
Mohammad Ebrahim Haji Naghi Tehrani1, 2, Mohammad Ramezanzadeh1, Ghasem Bahlakeh3, and Bahram Ramezanzadeh1, †
  • 1Department of Surface Coatings and Corrosion, Institute for Color Science and Technology, P.O. Box 16765-654, Tehran, Iran
  • 2School of Metallurgy and Materials Engineering, College of Engineering, University of Tehran, Tehran, Iran
  • 3Department of Chemical Engineering, Faculty of Engineering,, Golestan University, Aliabad Katoul, Iran
E-mail:
In this study, a novel anticorrosive pigment is introduced to fabricate a smart epoxy coating with biactive/ passive protection capabilities. For this purpose, the dual functionalized S, P-doped graphene oxide (GO) structure was synthesized through the rationed devised approach using phytic acid and polythiophene. The thiophene monomer was successfully polymerized on the modified rGO-Phytic acid (rGOPhy) sheets. It was observed that the polythiophene nano-scale particles well decorated the rGO-Phy surface, which was proved via Raman, FT-IR, UV-Vis, SEM-EDS, XRD, and TGA analyses. The developed nanocomposites were also introduced into the epoxy coating for anti-corrosive purposes. The corrosion retardation performance of the exerted coatings on the mild steel panels shows that the rGO-Phytic acid- Polythiophene (rGO-Phy-Pth) nano-composites inclusion into the epoxy composite coating endows the self-healing performance in line with the extraordinary barrier feature bring about the stable protection for almost 9 weeks. The achieved outstanding self-healing potential is assigned to the simultaneous controlled release of the polythiophene and phytic acid at the damaged area from the GO sheets, resulting in a film formation with increasing the resistance up to 50 kΩ cm2 while the blank sample demonstrated the decreasing trend.
Keywords:rGO-Phytic acid-polythiophene;Epoxy;Raman;EIS
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