염소함유 지방족 변성폴리에스테르의 합성과 이를 이용한 2성분계 폴리우레탄 난연도료의 물성

박흥수; 근장현; 염규설; 강두환; 임환빈

Polymer(Korea), Vol.19, No.6, 891-902, November, 1995

Syntheses and Physical Properties of Two-Component Polyurethane Flame Retardant Coatings Using Chlorine-containing Aliphatic Modified Polyesters

박흥수, 근장현, 염규설, 강두환, 임환빈

초록

난연성 지방족 카르복시산인 모노클로로아세트산의 함량을 10, 20, 30 wt%로 변화시키면서 1, 4-부탄디올, 트리메틸올프로판 및 아디프산과 축중합을 하여 염소함유 변성폴리에스테르(MCAO류)를 합성한 후에, MCAO류와 폴리이소시아네이트를 블렌드하여 2성분계 폴리우레탄 난연도료를 제조하였다. 제조된 난연도료의 제반 물성을 측정해 본 결과 비난연성 도료보다 물성이 떨어지지 않았고, 오히려 건조시간 측정에서 속건성을 나타내었으며, 가사시간이 9∼11시간으로 나타나 바람직한 속건성 난연도료임이 밝혀졌다. 또한 난면도료의 난연성 시험결과 수직법시 모노클로로아세트산 3wt %에서 불꽃에 타지 않아서 양호한 난연도료임이 입증되었다.

Two-component polyurethane flame retardant coatings were prepared by blending chlorine-containing modified polyesters (MCAOs) and polyisocyanate. MCAOs were synthesized by polycondensation of monochloroacetic acrid, a flame retardant aliphatic carboxylic acid, with 1,4-butanediol, trimethylolpropane, and adipic acid. The content of monochloroacetic acid was varied 10, 20, and 30 wt% for the reaction. These new flame retardant coatings showed various properties comparable to other non-flame retardant coatings. They were superior to flamable coatings from the experimental results showing rapid and 9 to 11 hours of pot-life. Coatings with 30 wt% monochloroacetic acid was not flamable by the vertical flame-retardancy test.

Keywords:two-component;polyurethane coatings;flame retardancy;modified polyester

[References]

Backus JK, Bernard DL, Darr WC, Saunders JH, J. Appl. Polym. Sci., 12, 1053 (1968)
Ishizawa M, Oshima H, Electro. Eng., 103, 35 (1983)
Anderson DG, Vanderberg JT, Anal. Chem., 57, 15 (1985)
Giudice CA, Delamo B, Eur. Coat. J., 11, 7 (1991)
Perrin DD, Armarego WLF, Purificationof Laboratory Chemicals," 3rd ed., p. 107, Pergamon Press, Oxford (1988)
Park HS, J. Korean Ind. Eng. Chem., 3(4), 670 (1992)
Xiao HX, Frisch KC, J. Coat. Technol., 61, 51 (1989)
Balkus JK, McAfee ER, Blue CD, McCarty CG, "Encyclopedia of Polymer Science and Engineering," 2nd ed., p. 289-290, John Wiley & Sons, Inc., New York (1989)
Park HS, Park EK, Kim SK, Chung KT, Polym.(Korea), 19(1), 19 (1995)
David WG, Official Digest, 33, 642 (1961)
Tehranisa M, Ryntz RA, Xiao HX, Kordomenos PI, Frisch KC, J. Coat. Technol., 59, 43 (1987)
Ballamy LJ, "The Infra-red Spectra of Complex Molecules," 4th ed., John Wiley & Sons, Inc., New York (1966)
Fresenius W, Huber JFK, Pungor E, Rechnitz GA, Simon W, West S, "Spectral Data for Structure Determination of organic Compounds," 2nd ed., Springer-Verlag, Berlin (1989)
Potter TA, Williams JL, J. Coat. Technol., 59, 749 (1987)
Patton TC, "Paint Flow and Figment Dispersion: A Rheological Approach to Coating and Ink Technology," 2nd ed., John Wiley & Sons, Inc., New York (1979)
Kuryla WC, Papa AJ, "Flame Retardancy of Polymeric Materials," p. 45, Marcel Dekker, Inc., New York (1980)
Yokouchi R, Nakamura I, "Polyester Fiber," 5th ed., p. 87, Korona Co. Ltd., Tokyo (1974)
Pohl HA, J. Am. Chem. Soc., 73, 5660 (1951)
Zimmerman H, Kim NT, Polym. Eng. Sci., 20, 680 (1980)
Schwenker RF, Beck LR, Text. Res. J., 30, 624 (1960)
Konishi H, Hirao C, "Flame Retardants," p. 42, Saiwai Shobo, Tokyo (1972)
Papa AJ, Proops WR, J. Appl. Polym. Sci., 17, 2463 (1973)
Fenimore CP, Martin FJ, Modern Plast., 44, 141 (1966)
Bostic JE, Yeh KN, Barker RH, J. Appl. Polym. Sci., 17, 471 (1973)
Mok YI, HWAHAK KONGHAK, 15(4), 211 (1977)

[Referenced By]

[1] Backus JK, Bernard DL, Darr WC, Saunders JH, J. Appl. Polym. Sci., 12, 1053 (1968)

[2] Ishizawa M, Oshima H, Electro. Eng., 103, 35 (1983)

[3] Anderson DG, Vanderberg JT, Anal. Chem., 57, 15 (1985)

[4] Giudice CA, Delamo B, Eur. Coat. J., 11, 7 (1991)

[5] Perrin DD, Armarego WLF, Purificationof Laboratory Chemicals," 3rd ed., p. 107, Pergamon Press, Oxford (1988)

[6] Park HS, J. Korean Ind. Eng. Chem., 3(4), 670 (1992)

[7] Xiao HX, Frisch KC, J. Coat. Technol., 61, 51 (1989)

[8] Balkus JK, McAfee ER, Blue CD, McCarty CG, "Encyclopedia of Polymer Science and Engineering," 2nd ed., p. 289-290, John Wiley & Sons, Inc., New York (1989)

[9] Park HS, Park EK, Kim SK, Chung KT, Polym.(Korea), 19(1), 19 (1995)

[10] David WG, Official Digest, 33, 642 (1961)

[11] Tehranisa M, Ryntz RA, Xiao HX, Kordomenos PI, Frisch KC, J. Coat. Technol., 59, 43 (1987)

[12] Ballamy LJ, "The Infra-red Spectra of Complex Molecules," 4th ed., John Wiley & Sons, Inc., New York (1966)

[13] Fresenius W, Huber JFK, Pungor E, Rechnitz GA, Simon W, West S, "Spectral Data for Structure Determination of organic Compounds," 2nd ed., Springer-Verlag, Berlin (1989)

[14] Potter TA, Williams JL, J. Coat. Technol., 59, 749 (1987)

[15] Patton TC, "Paint Flow and Figment Dispersion: A Rheological Approach to Coating and Ink Technology," 2nd ed., John Wiley & Sons, Inc., New York (1979)

[16] Kuryla WC, Papa AJ, "Flame Retardancy of Polymeric Materials," p. 45, Marcel Dekker, Inc., New York (1980)

[17] Yokouchi R, Nakamura I, "Polyester Fiber," 5th ed., p. 87, Korona Co. Ltd., Tokyo (1974)

[18] Pohl HA, J. Am. Chem. Soc., 73, 5660 (1951)

[19] Zimmerman H, Kim NT, Polym. Eng. Sci., 20, 680 (1980)

[20] Schwenker RF, Beck LR, Text. Res. J., 30, 624 (1960)

[21] Konishi H, Hirao C, "Flame Retardants," p. 42, Saiwai Shobo, Tokyo (1972)

[22] Papa AJ, Proops WR, J. Appl. Polym. Sci., 17, 2463 (1973)

[23] Fenimore CP, Martin FJ, Modern Plast., 44, 141 (1966)

[24] Bostic JE, Yeh KN, Barker RH, J. Appl. Polym. Sci., 17, 471 (1973)

[25] Mok YI, HWAHAK KONGHAK, 15(4), 211 (1977)