Effects of metal loading on activated carbon on its adsorption and desorption characteristics

Ji Hye Park; Ra Hyun Hwang; Hyung Chul Yoon; Kwang Bok Yi

Journal of Industrial and Engineering Chemistry, Vol.74, 199-207, June, 2019

DOI10.1016/j.jiec.2019.03.004 Export Citation

Effects of metal loading on activated carbon on its adsorption and desorption characteristics

Ji Hye Park, Ra Hyun Hwang, Hyung Chul Yoon¹, and Kwang Bok Yi^{2, †}

Graduate School of Energy Science and Technology, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon, 34134, South Korea
¹Korea Institute of Energy Research, 140, Yuseong-daero 1312 beon-gil, Yuseong-gu, Daejeon, 34101, South Korea
²Department of Chemical Engineering Education, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon, 34134, South Korea

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Metal loaded activated carbons (AC) were synthesized for an application in NH3 enrichment through repeated adsorption and desorption. The metal loaded activated carbons possesses higher NH3 adsorption capacity than the raw AC at room temperature. Mg loaded AC (AC-Mg) showed about 10 times (6.34 mg NH3/g) higher adsorption capacity than raw AC and its adsorption capacity was maintained even in repeated breakthrough tests. Metal loading on activated carbon increased the concentration of surface oxygen, which provides relatively weak adsorption sites for NH3 so that the adsorbed NH3 can be released relatively easier compared to the case of raw AC.

Keywords:Activated carbon;Metal;Ammonia;Adsorption;Desorption;Breakthrough test

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[Referenced By]

[1] Shipman MA, Symes MD, Catal. Today, 286, 57 (2017)

[2] Smil V, Nature, 400, 415 (1999)

[3] Jewell S, Kimball SM, U.S. Geol. Surv., 9, 196 (2015)

[4] Kim K, Lee SJ, Kim DY, Yoo CY, Choi JW, Kim JN, Woo Y, Yoon HC, Han JI, ChemSusChem, 11, 120 (2018)

[5] Chen S, Perathoner S, Ampelli C, Mebrahtu C, Su D, Centi G, Angew. Chem.-Int. Edit., 56, 2699 (2017)

[6] Jeong EY, Yoo CY, Jung CH, Park JH, Park YC, Kim JN, Oh SG, Woo Y, Yoon HC, ACS Sustainable Chem. Eng., 5, 9662 (2017)

[7] Kordali V, Kyriacou G, Lambrou C, Chem. Commun., 1673 (2000).

[8] Renner JN, Greenlee LF, Ayres KE, Herring AM, Electrochem. Soc. Interface, 24, 51 (2015)

[9] Lee CY, Choi JK, Yang HS, Nho YC, Appl. Chem., 2(2), 692 (1998)

[10] Bandosz TJ, Petit C, J. Colloid Interface Sci., 338(2), 329 (2009)

[11] Ghauri M, Tahir M, Abbas T, Khurram MS, Shehzad K, Sci. Int., 24, 411 (2012)

[12] Goncalves M, Sanchez-Garcia L, Jardim EDO, Silvestre-Albero J, Rodriguez-Reinoso F, Environ. Sci. Technol., 45, 10605 (2011)

[13] Guo J, Xu WS, Chen YL, Lua AC, J. Colloid Interface Sci., 281(2), 285 (2005)

[14] Huang CC, Li HS, Chen CH, J. Hazard. Mater., 159(2-3), 523 (2008)

[15] Kim SD, Magnone E, Park JH, Ryu JY, J. Porous Mat., 25, 297 (2018)

[16] Rieth AJ, Dinca M, J. Am. Chem. Soc., 140(9), 3461 (2018)

[17] Chen Y, Zhang F, Wang Y, Yang C, Yang J, Li J, Microporous Mesoporous Mater., 258, 170 (2018)

[18] Khabzina Y, Farrusseng D, Microporous Mesoporous Mater., 265, 143 (2018)

[19] Qajar A, Peer M, Andalibi MR, Rajagopalan R, Foley HC, Microporous Mesoporous Mater., 218, 15 (2015)

[20] Somy A, Mehrnia MR, Amrei HD, Ghanizadeh A, Safari M, Int. J. Greenhouse Gas Control, 3, 249 (2009)

[21] Huang CC, Chen HM, Chen CH, Huang JC, Sep. Purif. Technol., 70(3), 291 (2010)

[22] Othman FEC, Yusof N, Hasbullah H, Jaafar J, Ismail AF, Nasri NS, Carbon Lett., 24, 82 (2017)

[23] Chen TC, Agripa ML, Lu MC, Dalida MLP, Energy Fuels, 30(5), 3870 (2016)

[24] Bernal AMC, Gomez F, Pirajan JCM, Appl. Sci., 8(6), 843 (2018)

[25] Park SJ, Jin SY, J. Colloid Interface Sci., 286(1), 417 (2005)

[26] Park SJ, Kim BJ, J. Colloid Interface Sci., 291(2), 597 (2005)

[27] Tian X, Hong G, Liu Y, Jiang B, Yang Y, RSC Adv., 4, 36316 (2014)

[28] Al Amer AM, Laoui T, Abbas A, Al-Aqeeli N, Patel F, Khraisheh M, Atieh MA, Hilal N, Mater. Des., 89, 549 (2016)

[29] Baek JH, Lee SM, Park JH, Jeong JM, Hwang RH, Ko CH, Jeon SG, Choi TH, Yi KB, J. Ind. Eng. Chem., 48, 194 (2017)

[30] Phumman P, Niamlang S, Sirivat A, Sensors, 9, 8031 (2009)

[31] Yao XJ, Kong TT, Yu SH, Li LL, Yang FM, Dong L, Appl. Surf. Sci., 402, 208 (2017)

[32] Seredych M, Petit C, Tamashausky AV, Bandosz TJ, Carbon, 47, 445 (2009)

[33] Lee JH, Kim YH, Jung UC, Chung WS, Korean J. Met. Mater., 48, 218 (2010)

[34] Yao HB, Li Y, Wee ATS, Appl. Surf. Sci., 158(1-2), 112 (2000)

[35] Chen C, Splinter S, Do T, McIntyre N, Surf. Sci., 382, L652 (1997)

[36] Yang LX, Luan B, J. Electrochem. Soc., 152(7), C474 (2005)