화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.40, 168-176, August, 2016
DOI10.1016/j.jiec.2016.06.020  Export Citation
Ionic liquid incorporated nanocomposite polymer electrolytes for rechargeable lithium ion battery: A way to achieve improved electrochemical and interfacial properties
K. Karuppasamy1, 2, †, Hee Woo Rhee1, 3, P. Anil Reddy2, Dipti Gupta2, Liviu Mitu4, Anji Reddy Polu1, 5, and X. Sahaya Shajan6
  • 1Polymer Materials Lab, Department of Chemical and Biomolecular Engineering, Sogang University, Seoul, South Korea
  • 2Plastic Electronics and Energy Laboratory, Department of Metallurgical Engineering and Materials Science, Indian Institute of Technology Bombay, Powai 400 076, India
  • 3, Korea
  • 4Department of Natural Sciences, University of Pitesti, Pitesti 110 040, Romania
  • 5Department of Physics, Vardhaman College of Engineering (Autonomous), Kacharam, Shamshabad – 501218, Hyderabad, Telangana, India
  • 6Centre for Scientific and Applied Research, PSNCET, Tirunelveli 627 152, Tamil Nadu, India
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An ionic liquid incorporated nanocomposite electrolytes are prepared using solution cast technique by immobilizing a solution of lithium N,N-bis(trifluoromethanesulfonyl)imide (LiTFSI) in N-ethyl-N-methylimidazolium - bis(trifluoromethanesulfonyl) imide (EMImTFSI) ionic liquid (IL) with added mixtures of organic solvent and nanofiller such as acetonitrile and nanochitosan (32 nm) into a poly(ethylene oxide) (PEO) matrix. The achieved extreme ionic conductivity of ionic liquid based electrolyte is in the range of 10-2 S cm-1 which is one order higher than that of (PEO)8LiTFSI-10 wt% NC system. Cyclic voltammetry and linear sweep voltammetry (LSV) analyses indicates that the prepared electrolytes possesses an excellent electrochemical stability of 3.9 V. These unique properties allow the effective use of these membranes as active separators for the development of advanced lithium ion batteries.
Keywords:Ionic liquid;Cyclic voltammetry;Ionic conductivity;Solution cast method
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